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In which of the following molecule/ion a...

In which of the following molecule/ion all the bonds are not equal?

A

`XeF_(4)`

B

`BF_(4)^(-)`

C

`C_(2)H_(4)`

D

`SiF_(4)`

Text Solution

AI Generated Solution

The correct Answer is:
To determine which molecule or ion has unequal bond lengths, we can analyze the given options one by one. ### Step-by-Step Solution: 1. **Identify the Molecules/Ions:** The options given are XCF4, SF4, C2H4, and SiF4. 2. **Analyze XCF4 (Xenon Tetrafluoride):** - **Valence Electrons Calculation:** - Xenon (Xe) has 8 valence electrons. - Each fluorine (F) has 1 valence electron, and there are 4 fluorines: 4 × 1 = 4. - Total = 8 + 4 = 12 valence electrons. - **Hybridization:** - The hybridization is determined to be sp³d² (6 electron pairs: 4 bond pairs and 2 lone pairs). - **Molecular Geometry:** - The shape is square planar. - All bond lengths are equal in this configuration. - **Conclusion:** All bonds are equal in XCF4. 3. **Analyze SF4 (Sulfur Tetrafluoride):** - **Valence Electrons Calculation:** - Sulfur (S) has 6 valence electrons. - Each fluorine has 1 valence electron, and there are 4 fluorines: 4 × 1 = 4. - Total = 6 + 4 = 10 valence electrons. - **Hybridization:** - The hybridization is sp³d (5 electron pairs: 4 bond pairs and 1 lone pair). - **Molecular Geometry:** - The shape is see-saw. - The presence of a lone pair leads to unequal bond lengths. - **Conclusion:** Not all bonds are equal in SF4. 4. **Analyze C2H4 (Ethylene):** - **Structure:** - Ethylene has a double bond between the two carbon atoms and single bonds to hydrogen atoms. - **Bond Types:** - The presence of a double bond (C=C) and single bonds (C-H) leads to different bond lengths. - **Conclusion:** Not all bonds are equal in C2H4. 5. **Analyze SiF4 (Silicon Tetrafluoride):** - **Valence Electrons Calculation:** - Silicon (Si) has 4 valence electrons. - Each fluorine has 1 valence electron, and there are 4 fluorines: 4 × 1 = 4. - Total = 4 + 4 = 8 valence electrons. - **Hybridization:** - The hybridization is sp³ (4 bond pairs and 0 lone pairs). - **Molecular Geometry:** - The shape is tetrahedral. - All bond lengths are equal in this configuration. - **Conclusion:** All bonds are equal in SiF4. 6. **Final Conclusion:** - The molecules where not all bonds are equal are C2H4 and SF4. However, since the question asks for a single option, the most distinct case is C2H4 due to the presence of a double bond. ### Answer: The molecule in which all the bonds are not equal is **C2H4**.

To determine which molecule or ion has unequal bond lengths, we can analyze the given options one by one. ### Step-by-Step Solution: 1. **Identify the Molecules/Ions:** The options given are XCF4, SF4, C2H4, and SiF4. 2. **Analyze XCF4 (Xenon Tetrafluoride):** ...
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