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Which of the following have identical bo...

Which of the following have identical bond order?

A

`CN^(-)`

B

`NO^(+)`

C

`O_(2)^(-)`

D

`O_(2)^(2-)`

Text Solution

AI Generated Solution

The correct Answer is:
To determine which of the given species have identical bond orders, we need to calculate the bond order for each species based on the number of electrons present. Here’s a step-by-step solution: ### Step 1: Identify the species Let's assume the species in question are CN⁻ (cyanide ion), NO⁺ (nitric oxide cation), O₂ (dioxygen), and O₂²⁻ (peroxide ion). ### Step 2: Calculate the total number of electrons for each species 1. **CN⁻**: - Carbon (C) has 4 electrons. - Nitrogen (N) has 5 electrons. - The negative charge (-1) adds 1 electron. - Total = 4 (C) + 5 (N) + 1 = 10 electrons. 2. **NO⁺**: - Nitrogen (N) has 5 electrons. - Oxygen (O) has 6 electrons. - The positive charge (+1) removes 1 electron. - Total = 5 (N) + 6 (O) - 1 = 10 electrons. 3. **O₂**: - Each oxygen (O) has 6 electrons. - Total = 6 (O) + 6 (O) = 12 electrons. 4. **O₂²⁻**: - Each oxygen (O) has 6 electrons. - The two negative charges (-2) add 2 electrons. - Total = 6 (O) + 6 (O) + 2 = 14 electrons. ### Step 3: Compare the total number of electrons - CN⁻ has 10 electrons. - NO⁺ has 10 electrons. - O₂ has 12 electrons. - O₂²⁻ has 14 electrons. ### Step 4: Identify species with identical bond orders From the calculations: - CN⁻ and NO⁺ both have 10 electrons. - O₂ has 12 electrons. - O₂²⁻ has 14 electrons. Since CN⁻ and NO⁺ have the same number of electrons, they will have identical bond orders. ### Conclusion The species that have identical bond orders are **CN⁻ and NO⁺**. ---

To determine which of the given species have identical bond orders, we need to calculate the bond order for each species based on the number of electrons present. Here’s a step-by-step solution: ### Step 1: Identify the species Let's assume the species in question are CN⁻ (cyanide ion), NO⁺ (nitric oxide cation), O₂ (dioxygen), and O₂²⁻ (peroxide ion). ### Step 2: Calculate the total number of electrons for each species 1. **CN⁻**: - Carbon (C) has 4 electrons. ...
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