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Which of the following attain the linear...

Which of the following attain the linear structure ?

A

`BeCl_(2)`

B

`NCO^(+)`

C

`NO_(2)`

D

`CS_(2)`

Text Solution

Verified by Experts

The correct Answer is:
A, D

(a,d) `BeCl_(2)(Cl-Be-Cl)` and `CS_(2)(S=C=S)` both are linear. `NCO^(+)` is non-linear. However, [remember that `NCO(-N=C=O)` is linear because it is isoelectric with `CO_(2)`. `NO_(2)` is angualr with bond angle `132^(@)` and each O-N bond begin of `1.20Å` (intermediate between single and double bond).
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