Home
Class 12
CHEMISTRY
For the reaction : C(2)H(5)I+OH^(-) ra...

For the reaction :
`C_(2)H_(5)I+OH^(-) rarr C_(2)H_(5)OH + I^(-)`
the rate constant was found to have a value of `5.03xx10^(-2)" mol"^(-1)" dm"^(3) s^(-1)" at "289 K and 6.71" mol"^(-1)" dm"^(3) s^(-1)` at 333 K What is the rate constant at 305 K.

Text Solution

AI Generated Solution

To find the rate constant at 305 K for the given reaction, we will use the Arrhenius equation and the provided rate constants at two different temperatures. Here’s a step-by-step solution: ### Step 1: Write down the given data We have: - \( K_1 = 5.03 \times 10^{-2} \, \text{mol}^{-1} \, \text{dm}^3 \, \text{s}^{-1} \) at \( T_1 = 289 \, \text{K} \) - \( K_2 = 6.71 \, \text{mol}^{-1} \, \text{dm}^3 \, \text{s}^{-1} \) at \( T_2 = 333 \, \text{K} \) We need to find \( K_3 \) at \( T_3 = 305 \, \text{K} \). ...
Promotional Banner

Topper's Solved these Questions

  • Chemical Kinetics

    MOTION|Exercise Exercise -1 (Introduction, Rate of reaction, Factor affecting rate of reaction, Effect of concentration on reaction rate)|9 Videos
  • Chemical Kinetics

    MOTION|Exercise Exercise -1 (Zero order reaction, 1st order reaction , 2nd order reaction & nth order reaction)|11 Videos
  • Chemical Kinetics

    MOTION|Exercise SOLVED EXAMPLE (OBJECTIVE)|10 Videos
  • CHEMICAL EQUILIBRIUM

    MOTION|Exercise Exercise - 4|20 Videos
  • CLASSROOM PROBLEMS

    MOTION|Exercise Electrochemistry|22 Videos

Similar Questions

Explore conceptually related problems

The rate constant for a given reaction is K=3xx10^(-5)S^(-1)" atm"^(-1) . Express it in units of L" mol"^(-1) sec^(-1) .

The rate constant of a reaction is 1.2xx10^(-5)mol ^(-2)"litre"^(2) S^(-1) the order of the reaction is

The gas phase reaction 2NO_(2)+O_(3)rarrN_(2)O_(5)+O_(2) has the rate constant k = 2.0xx10^(-4) dm^(3) mol^(-1) s^(-1) at 300 K. The order of the reaction is

For the reaction: [Cr(H_(2)O)_(6)]^(3) + [SCN^(ɵ)] rarr [Cr(H_(2)O)_(5)NCS]^(2+)H_(2)O The rate law is r = k[Cr(H_(2)O)_(6)]^(3+)[SCN^(ɵ)] . The value of k is 2.0 xx 10^(-6) L mol^(-1) s^(-1) at 14^(@)C and 2.2 xx 10^(-5) L mol^(-1)s^(-1) at 30^(@)C . What is the value of E_(a) ?

For the inversion of cane, sugar, C_(12)H_(22)O_(11)+H_(2)OrarrC_(6)H_(12)O_(6)+C_(6)H_(12)O_(6) , the rate constant is 2.12xx10^(-4) L "mol"^(-1) "sec"^(-1) "at" 27^(@)C . The activation energy of the reaction is 1.07xx10^(5) K "mol"^(-1) . What is the rate constant of the reaction at 37^(@)C

The rate constant for the reaction in gaseous phase O+O_(3) rarr 2O_(2) is 8.0xx10^(-15)" cm"^(3)" molecule"^(-1) s^(-1) at 298 K. Corresponding value in dm^(3)" mol"^(-1) s^(-1) is :

MOTION-Chemical Kinetics-SOLVED EXAMPLE (SUBJECTIVE)
  1. The reaction given below, rate constant for disappearance of A is 7.48...

    Text Solution

    |

  2. The net rate of reaction of the change : [Cu(NH(3))(4)]^(2+)+H(2)O ?...

    Text Solution

    |

  3. The net rate of reaction of the change : [Cu(NH(3))(4)]^(2+)+H(2)O ?...

    Text Solution

    |

  4. The net rate of reaction of the change : [Cu(NH(3))(4)]^(2+)+H(2)O ?...

    Text Solution

    |

  5. The rate law for the decompoistion of gaseous N(2)O(5), N(2)O(5)(g) ...

    Text Solution

    |

  6. The half time of first order decomposition of nitramide is 2.1 hour at...

    Text Solution

    |

  7. The half time of first order decomposition of nitramide is 2.1 hour at...

    Text Solution

    |

  8. The reaction A+OH^(-)rarr Products, obeys rate law expression as : (...

    Text Solution

    |

  9. A certain reaction A + B rarr Products is first order w.r.t. each reac...

    Text Solution

    |

  10. Dimethyl ether decomposes according to the following reaction : CH(3...

    Text Solution

    |

  11. The decomposition of N(2)O(5) according to following reaction is first...

    Text Solution

    |

  12. The gas phase decomposition of N(2)O(5)" to "NO(2) and O(2) is monitor...

    Text Solution

    |

  13. 5 ml of ethylacetate was added to a flask containing 100 ml f 0.1 N HC...

    Text Solution

    |

  14. The optical rotations of sucrose in 0.5N HCl" at "35^(@)C at various t...

    Text Solution

    |

  15. The hydrolysis of ethyl acetate CH(3)COOC(2)H(3)+H(2)O hArr CH(3) CO...

    Text Solution

    |

  16. Two first order reactions proceed at 25^(@)C at the same rate. The tem...

    Text Solution

    |

  17. For the reaction : C(2)H(5)I+OH^(-) rarr C(2)H(5)OH + I^(-) the ra...

    Text Solution

    |

  18. A secondary alkyl halide (RX) is hydrolysed by alkali simultaneously b...

    Text Solution

    |

  19. A polymerisation reaction is carried out at 2000 K and the same reacti...

    Text Solution

    |

  20. Consider the following first order parallel reaction. The concent...

    Text Solution

    |