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A overset(k) rarrB, t(1//2)=10" min "3A ...

`A overset(k) rarrB, t_(1//2)=10" min "3A rarrC`
Both reaction have same rate constant and each occurring following first order kinetics. Choose the correct option for second reaction.

A

`t_(1//2)=10//3" min"`

B

`t_(1//2)=30" min"`

C

`t_(1//2)=10" min"`

D

Data insufficient

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we need to determine the half-life of the second reaction, which is given as \(3A \rightarrow C\), knowing that both reactions follow first-order kinetics and have the same rate constant \(k\). ### Step-by-Step Solution: 1. **Understanding First-Order Kinetics**: - For a first-order reaction, the half-life (\(t_{1/2}\)) is given by the formula: \[ t_{1/2} = \frac{\ln 2}{k} \] - The half-life is independent of the initial concentration. 2. **Given Information**: - The half-life for the reaction \(A \rightarrow B\) is given as \(10 \text{ minutes}\). Thus: \[ t_{1/2} = 10 \text{ minutes} = \frac{\ln 2}{k} \] - From this, we can find the rate constant \(k\): \[ k = \frac{\ln 2}{10 \text{ minutes}} \] 3. **Analyzing the Second Reaction**: - The second reaction is \(3A \rightarrow C\). This is also a first-order reaction, but the stoichiometry indicates that three moles of \(A\) are consumed to produce one mole of \(C\). - For a reaction of the form \(nA \rightarrow \text{products}\), the rate of reaction can be expressed as: \[ -\frac{1}{n} \frac{d[A]}{dt} = k[A] \] - For our case, \(n = 3\), so: \[ -\frac{1}{3} \frac{d[A]}{dt} = k[A] \] 4. **Integrating the Rate Equation**: - Rearranging gives: \[ d[A] = -3k[A]dt \] - Integrating from \(t = 0\) to \(t\) and from \([A]_0\) to \([A]_t\): \[ \int_{[A]_0}^{[A]_t} \frac{d[A]}{[A]} = -3k \int_0^t dt \] - This results in: \[ \ln \left(\frac{[A]_0}{[A]_t}\right) = -3kt \] 5. **Finding Half-Life for the Second Reaction**: - At half-life, \([A]_t = \frac{[A]_0}{2}\): \[ \ln \left(\frac{[A]_0}{\frac{[A]_0}{2}}\right) = -3k t_{1/2} \] - This simplifies to: \[ \ln(2) = -3k t_{1/2} \] - Solving for \(t_{1/2}\): \[ t_{1/2} = \frac{\ln(2)}{3k} \] 6. **Substituting the Value of \(k\)**: - We already found \(k = \frac{\ln 2}{10}\): \[ t_{1/2} = \frac{\ln(2)}{3 \cdot \frac{\ln(2)}{10}} = \frac{10}{3} \text{ minutes} \] ### Final Answer: The half-life for the second reaction \(3A \rightarrow C\) is: \[ t_{1/2} = \frac{10}{3} \text{ minutes} \approx 3.33 \text{ minutes} \]
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