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The data given below are for the reactio...

The data given below are for the reaction of `NO` and `Cl_(2)` to from `NOCl` at `295 K`.
`{:([Cl_(2)],[NO],,,"Initial rate" (mol litre^(-1) sec^(-1))),(0.05,0.05,,,1xx10^(-3)),(0.15,0.05,,,3xx10^(-3)),(0.05,0.15,,,9xx10^(-3)):}`
(a) What is the order with respect to `NO` and `Cl_(2)` in the reaction?
(b) Write the rate expression.
(c ) Calculate the rate constant.
(d) Determine the reaction rate when conc. of `Cl_(2)` and `NO` are `0.2 M` and `0.4 M` respectively.

Text Solution

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(a) order w.r.t NO=2 and w.r.t `Cl_(2) =1`, (b) `r=K[NO]^(2)[Cl_(2)], (c ) K=8L^(2)" mol"^(-2) s^(-1)` (d) rate =`0.256" mole L"^(-1) s^(-1)`
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