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(CH(3)COO)(2)Ca+(HCOO)(2)Caoverset("Heat...

`(CH_(3)COO)_(2)Ca+(HCOO)_(2)Caoverset("Heat")rarr`

A

Propanone

B

Methanal

C

Ethanal

D

One of the above

Text Solution

Verified by Experts

The correct Answer is:
D
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Which of the following will produce isopropyl amine - (I) (CH_(3))_(2)CO overset(NH_(2)OH)rarr X overset(LiAlH_(4))rarr (II) CH_(3)-CH_(2)-CHO overset(NH_(3))underset("heat")rarr X overset(LiAlH_(4))rarr (III) (CH_(3))_(2)CH-OH+PCl_(5)rarr X overset(NH_(3))rarr (IV) CH_(3)-CH_(2)-CH_(2)-NH_(2)overset("heat")rarr

Complete the following and identify the type for the inter-mediate species: (a) CH_(3)CH(OH)CH_(3)+H^(+)overset("Heat")rarr………+HOH (b) CH_(3)-C-=C-H+Na^(+)NH_(2)^(-)rarr …….+Na^(+)+NH_(3) (c) CH_(3)CH_(2)-N=N-CH_(2)CH_(3)overset("Heat")rarr......+N_(2) (d) CH_(3)-CH=CH-CH_(3)+HIrarr ........+I^(-) (e) CH_(3)CHI_(2)+Znrarr ........+ZnI_(2) (f) CH_(3)CH_(2)Cl+AlCl_(3)rarr .....+AlCl_(4)

Complete the following : (i) (CH_(3)COO)_(2)Caoverset("Heat")rarr , (ii) CH_(3)CH_(2)OHoverset("Cu"//573K)rarr , (iii) CH_(3)CHOoverset(NaOH("dil"))rarr , (iv) C_(6)H_(5)COCloverset(H_(2))underset(Pd//BaSO_(4))rarr (v) C_(6)H_(5)COCl overset((CH_(3))_(2)//Cd)rarr

(CH_(3))_(3)C CH_(2)-CBr(CH_(3))_(2)overset(Heat)rarr The major product is

In the reaction, the produces formed are (CH_(3))_(2)CH_(2).CH_(2).O.CH_(2)CH_(3)+HI overset(Heated)rarr

Write the structure of the major product and IUPAC name in each of the following reactions : (i) CH_(3)CH_(2)CH_(2)Cl+NaI underset("Heat")overset("Acetone")to (ii) CH_(3)CH_(2)Cl + SbF_(3) overset("Heat")rarr (iii) CH_(3)CH_(2)CH_(2)OH +SOCI_(2) rarr (iv) CH_(3)CH_(2)CH=CH_(2)+HBr overset("Peroxide")rarr (v) CH_(3)CH_(2)underset(CH_(3))underset(|)C=CH_(2)+HBr overset("No Peroxide")rarr (vi) CH_(3)CH_(2)CH_(2)Br+Hg_(2)F_(2) rarr (vii) CH_(3)CH_(2)C-= CH+HCl ("1-equiv") rarr (viii) CH_(3)CH=CH_(2)+Cl_(2)overset(773-873k)rarr

Write the structure of the major product and IUPAC name in each of the following reactions : (i) CH_(3)CH_(2)CH_(2)Cl+NaI underset("Heat")overset("Acetone")to (ii) CH_(3)CH_(2)Cl + SbF_(3) overset("Heat")rarr (iii) CH_(3)CH_(2)CH_(2)OH +SOCl_(2) rarr (iv) CH_(3)CH_(2)CH=CH_(2)+HBr overset("Peroxide")rarr (v) CH_(3)CH_(2)underset(CH_(3))underset(|)C=CH_(2)+HBr overset("No Peroxide")rarr (vi) CH_(3)CH_(2)CH_(2)Br+Hg_(2)F_(2) rarr (vii) CH_(3)CH_(2)C-= CH+HCl ("1-equiv") rarr (viii) CH_(3)CH=CH_(2)+Cl_(2)overset(773-873k)rarr

Write the structure of the major organic product in each of the following reactions: (i) CH_(3)CH_(2)CH_(2)Cl + NaI underset("heat")overset("acetone")rarr (ii) (CH_(3))_(3)CBr + KOH underset("heat")overset("ethanol")rarr (iii) CH_(3)CH(Br)CH_(2)CH_(3) + NaOH overset("water")rarr (iv) CH_(3)CH_(2)Br + KCN overset("aq. ethanol")rarr (v) C_(6)H_(5)ONa + C_(2)H_(5)Cl rarr (vi) CH_(3)CH_(2)CH_(2)OH + SOCl_(2) rarr (vii) CH_(3)CH_(2)CH = CH_(2) + HBr overset("peroxide")rarr (viii) CH_3CH = C(CH_3)_2 + HBr rarr

MOTION-CARBONL COMPOUNDS-EXERCISE -1
  1. When CH(3)MgI reacts with CH(3)CN and the product is hydrolysed, we ge...

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  2. Ethylidene chloride (CH(3)CHCl(2)) on hydrolysis with NaOH gives -

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  3. (CH(3)COO)(2)Ca+(HCOO)(2)Caoverset("Heat")rarr

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  4. A underset(H(2))overset(Pd//BaSO(4))(rarr) ph-CHO underset((ii)H(2)O)o...

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  5. The reaction - CH(3)COCl + H(2) underset(Pd//BaSO(4))overset("Xylene...

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  6. What is the function of BaSO4 in Rosenmund reactionn -

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  7. The reaction of ethyl formate with excess of CH(3)MgI followed by hydr...

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  8. Compound used for preserving dead bodies is -

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  9. Which of the following forces is correctly described about boiling po...

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  10. Which aldehyde is insoluble in H(2)O -

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  11. The general order of reactivity of carbonyl compounds for nucleophilic...

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  12. Least reactive towards nucleophilic additon is

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  13. What would be the product when acetaldehyde reacts with HCN and the pr...

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  14. Reaction of ammonia derivative with carbonyl compound is an example of...

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  15. The vapour density of a compound is 29, which reacts with iodine and N...

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  16. In connection with benzaldehyde which of the following statement is in...

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  17. A ketone reacted with ethyl magnesium bromide followed by hydrolysis g...

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  18. The reaction , 2RCHO overset("Al-ethoxide")(rarr) RCOOCH(2)R is called...

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  19. Aldol condensation between following compounds, followed by dehydratio...

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  20. In Cannizzaro reaction-

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