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Gem dilhalide on hydrolysis gives:...

Gem dilhalide on hydrolysis gives:

A

Vic diol

B

Gem diol

C

Carbonyl compound

D

Carboxylic acid

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question about the products formed from the hydrolysis of a geminal dihalide, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Structure of Geminal Dihalide:** - A geminal dihalide is a compound where two halogen atoms are attached to the same carbon atom. For example, consider a compound like CH3-CH(Cl)(Cl)-CH3, where two chlorine atoms are bonded to the same carbon. 2. **Understand Hydrolysis:** - Hydrolysis is a chemical reaction involving the breaking of a bond in a molecule using water. In this case, we will use potassium hydroxide (KOH) to facilitate the reaction. 3. **Nucleophilic Substitution:** - In the presence of KOH, the hydroxide ion (OH⁻) acts as a nucleophile. It will attack the carbon atom bonded to the halogens (Cl in this case) and replace the halogen atoms. - The reaction can be represented as follows: - CH3-CH(Cl)(Cl)-CH3 + 2 KOH → CH3-CH(OH)(OH)-CH3 + 2 KCl 4. **Formation of the Product:** - After the nucleophilic substitution, we will have a compound with two hydroxyl (OH) groups on the same carbon atom. This compound is CH3-CH(OH)(OH)-CH3. 5. **Stability Consideration:** - Compounds with two hydroxyl groups on the same carbon are not stable. To achieve stability, a water molecule (H2O) will be eliminated from the compound. - The elimination can be represented as: - CH3-CH(OH)(OH)-CH3 → CH3-CH=CH2 + H2O 6. **Final Product:** - The final product after hydrolysis and subsequent dehydration is an alkene, specifically propene (CH3-CH=CH2). ### Final Answer: The hydrolysis of a geminal dihalide gives an alkene as the final product, typically after the removal of water. ---
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Knowledge Check

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