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C(6)H(5) "COCl" underset(H(2))overset(Pd...

`C_(6)H_(5) "COCl" underset(H_(2))overset(Pd-BaSO_(4))(rarr)` Intermediate
`overset(" Oxidation ")(rarr)` Intermediate`underset("Dry distillation")overset("Ca-Salt")(rarr)` A
Compound (A) in above reaction sequence is –

A

Benzophenone

B

Benzaldehyde

C

Acetophenone

D

Benzoquinone

Text Solution

AI Generated Solution

The correct Answer is:
To solve the given reaction pathway, we will break it down step by step. ### Step 1: Identify the starting compound The starting compound is Benzoyl Chloride, which is represented as \( C_6H_5COCl \). ### Step 2: Perform the Rosenmund Reaction Benzoyl Chloride reacts with hydrogen in the presence of palladium on barium sulfate (Pd-BaSO4). This reaction is known as the Rosenmund reaction, which reduces the acyl chloride to an aldehyde. **Intermediate formed:** - The product of this reaction is Benzaldehyde (\( C_6H_5CHO \)). ### Step 3: Oxidation of Benzaldehyde Next, we take the intermediate Benzaldehyde and oxidize it. Aldehydes can be oxidized to carboxylic acids. **Intermediate formed:** - The oxidation of Benzaldehyde results in the formation of Benzoic Acid (\( C_6H_5COOH \)). ### Step 4: Reaction with Calcium Salt Now, we react Benzoic Acid with a calcium salt (for example, Calcium Hydroxide). In this reaction, the carboxylic acid groups will react with calcium, forming a calcium salt of the acid. **Intermediate formed:** - This results in a compound that can be represented as Calcium Benzoate. ### Step 5: Dry Distillation Finally, we perform dry distillation on the calcium salt. During this process, calcium carbonate (CaCO3) is released, and the remaining components will lead to the formation of a new compound. **Final product (Compound A):** - The product of this reaction is Benzophenone (\( C_6H_5COC_6H_5 \)), which consists of two phenyl groups connected by a carbonyl group. ### Conclusion The compound (A) in the above reaction sequence is **Benzophenone**. ---
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MOTION-CARBONL COMPOUNDS-EXERCISE -1
  1. A ketone reacted with ethyl magnesium bromide followed by hydrolysis g...

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  2. The reaction , 2RCHO overset("Al-ethoxide")(rarr) RCOOCH(2)R is called...

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  3. Aldol condensation between following compounds, followed by dehydratio...

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  4. In Cannizzaro reaction-

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  5. HCHO with conc. alkali forms two compounds. The change in oxidation nu...

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  6. Which is most difficult to oxidise-

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  7. C(6)H(5) "COCl" underset(H(2))overset(Pd-BaSO(4))(rarr) Intermediate ...

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  8. C(6)H(5)CHO overset(NH(2)OH)(rarr)" A " overset(H(2)O)(rarr) B What ...

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  9. Benzaldehyde can be converted to benzyl alcohol by –

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  10. Benzaldehyde condenses with acetic anhydride to give cinnamic acid in ...

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  11. ? underset(ETOH(2)H(2)O)overset(Delta, CN^(-))(rarr) Benzoin. The rea...

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  12. C(6)H(5)CHO overset(Cl(2))(rarr) A + HCl The product A when reacts ...

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  13. Acetone shows similarity with acetaldehyde in reacting to-

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  14. Which statement is true about benzaldehyde

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  15. Which of the following combinations give t-butyl alcohol when treated ...

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  16. The conversion CH(3)CH(2)CHO "––––"rarr CH(3)CH(2)CH(2)OH can not be a...

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  17. Which of the following can be used to differentiate between ethanal an...

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  18. Fehling’s solution –B is-

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  19. Acetone gives test with-

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  20. Which of the following does not turn Schiff's reagent to pink?

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