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Acetone shows similarity with acetaldehy...

Acetone shows similarity with acetaldehyde in reacting to-

A

Schiff’s reagent

B

Fehling solution

C

Grignard reagent

D

Tollen’s reagent

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The correct Answer is:
To determine the similarity in reactivity between acetone and acetaldehyde, we need to analyze their reactions with various reagents. ### Step-by-Step Solution: 1. **Identify the Functional Groups**: - Acetaldehyde (CH3CHO) contains an aldehyde functional group. - Acetone (CH3COCH3) contains a ketone functional group. 2. **Reactions with Schiff's Reagent**: - Schiff's reagent reacts primarily with aldehydes to produce a bright red color. - While acetone (ketone) can react with Schiff's reagent, it is not typically used for this purpose. Therefore, this similarity is not significant. 3. **Reactions with Fehling's Solution**: - Fehling's solution is known to react with aldehydes to produce a red precipitate of copper(I) oxide. - Ketones do not react with Fehling's solution. Hence, this is not a point of similarity. 4. **Reactions with Tollens' Reagent**: - Tollens' reagent (ammoniacal silver nitrate) reacts with aldehydes to form a silver mirror and oxidizes the aldehyde to a carboxylic acid. - Ketones do not react with Tollens' reagent. Therefore, this is also not a similarity. 5. **Reactions with Grignard Reagent**: - Grignard reagents (e.g., CH3MgBr) react with both aldehydes and ketones through nucleophilic addition. - For acetaldehyde, the reaction with Grignard reagent produces a secondary alcohol after hydrolysis. - For acetone, the reaction with Grignard reagent also produces a tertiary alcohol after hydrolysis. - This indicates that both acetaldehyde and acetone can react with Grignard reagents, demonstrating a similarity in their reactivity. 6. **Conclusion**: - The only significant similarity in reactivity between acetone and acetaldehyde is their reaction with Grignard reagents. ### Final Answer: Acetone shows similarity with acetaldehyde in reacting to **Grignard Reagent**. ---
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