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The acid formed when propyl magnesium br...

The acid formed when propyl magnesium bromide is treated with `CO_(2)` is -

A

`CH_(3)CH_(2)COOH`

B

`C_(3)H_(7)COOH`

C

`CH_(3)CH_(2)CH_(2)CH_(2)COOH`

D

None

Text Solution

AI Generated Solution

The correct Answer is:
To determine the acid formed when propyl magnesium bromide is treated with carbon dioxide, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Grignard Reagent**: Propyl magnesium bromide (C3H7MgBr) is a Grignard reagent. It consists of a propyl group (C3H7) bonded to a magnesium bromide (MgBr). 2. **Reaction with Carbon Dioxide**: When the Grignard reagent reacts with carbon dioxide (CO2), the nucleophilic carbon of the propyl group attacks the electrophilic carbon of the carbon dioxide molecule. This results in the formation of a carboxylate intermediate. \[ \text{C}_3\text{H}_7\text{MgBr} + \text{CO}_2 \rightarrow \text{C}_3\text{H}_7\text{COO}^- \text{MgBr}^+ \] 3. **Formation of Carboxylic Acid**: The carboxylate ion (C3H7COO^-) can then undergo hydrolysis. In hydrolysis, water (H2O) reacts with the carboxylate ion to form the corresponding carboxylic acid. \[ \text{C}_3\text{H}_7\text{COO}^- + \text{H}_2\text{O} \rightarrow \text{C}_3\text{H}_7\text{COOH} + \text{OH}^- \] 4. **Naming the Acid**: The resulting carboxylic acid is propanoic acid (C3H7COOH), which is also known as propionic acid. It has three carbon atoms in the chain. ### Final Answer: The acid formed when propyl magnesium bromide is treated with carbon dioxide is **propanoic acid (propionic acid)**. ---
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MOTION-CARBOXYLIC ACID-Exercise - 4 (LEVEL - 2 )
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  2. The IUPAC name of C(6)H(5)COCl is

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  3. Which of the following reactants on reaction with conc. NaOH followed ...

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  4. Match the compounds in Column I with their characteristic test(s)/reac...

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  5. Match each of the compounds given in Column I with the reaction(s), th...

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  6. The major product of the following reaction is

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  7. Among the following compounds, the most acidic is

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  8. The carboxyl functional group (-COOH) is present in :

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  9. The compound that undergoes decarboxylation most readily under mild c...

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  10. After completion of the reaction (I and II), the organic compound(s) i...

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  11. P and Q are isomers of dicarboxylic acid C(4)H(4)O(4). Bothdecolorize ...

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  12. P and Q are isomer of dicraboxylic acid C(4)H(4)O(4) Both decolourixe ...

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  13. In the reaction shown, below, the major product(s) formed is/are :

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  14. Consider all possible isomeric ketones, including stereoisomers, of MW...

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  15. The product(s) of the following reaction sequence is(are):

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  16. Compound p and R upon ozonolysis produce Q and S, respectively . Th...

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  17. Columns 1,2 and 3 contain starting materials, reaction conditions, and...

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  18. Columns 1,2 and 3 contain starting materials, reaction conditions, and...

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  19. Columns 1,2 and 3 contain starting materials, reaction conditions, and...

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  20. Aniline reacts with mixed acid (cone. HNO(3) and cone. H(2)SO(4)) at 2...

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  21. Treatment of benzene with CO/HCl in the presence of anhydrous "AlCl"(3...

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