Home
Class 12
CHEMISTRY
Magnesium oxide has the NaCl structure a...

Magnesium oxide has the NaCl structure and radii of `Mg^(2+)` and `O^(2–)` ions are 0.86 A and 1.24 A. Determine the density of magnesium oxide solid.

Text Solution

Verified by Experts

In a unit cell, there are four unit of MgO and edge- length of the unit cell is
a = 2 (radius of cation + radius of anion)
= 2 (0.86 + 1.24) = 4.2 Å
Density `(rho)=(4x40)/(6.023xx10^(23)(4.2xx10^(10^(-8)))^(3))=3.585 g//cc`
Promotional Banner

Topper's Solved these Questions

  • SOLID STATE

    MOTION|Exercise Exercise - 1 (Crystalline & amorphous solids, Classification of crystalline solids)|31 Videos
  • SOLID STATE

    MOTION|Exercise Exercise - 1 (Types of cubic unit cell SCC, BCC, FCC )|1 Videos
  • SOLID STATE

    MOTION|Exercise Exercise - 4 | Level-II|9 Videos
  • Salt Analysis

    MOTION|Exercise Exercise - 4 Level-II|22 Videos
  • SURFACE CHEMISTRY

    MOTION|Exercise Exercise - 3 (Level-II)|12 Videos

Similar Questions

Explore conceptually related problems

CdO has NaCl like structure with density 8.27g//c c . If the ionic radius of O^(2-) is 1.24A^(@) determine the ionic radius of Cd^(2+) :

Ferrous oxide has a cubie structure and edge length of the uint cell is 5.0Å . Assuming the density o ferrous oxide to be 3.84 g//cm^(3) , the no. Of Fe^(2+) and O^(2-) ions present in each unit cell be : (use N_(A)= 6xx 10^(23) ):

In an experiment to determine the empirical formula of magnesium oxide, a student weights an empty crucible then adds a strip of magnesium metal and reweighs the crucible. The crucible and magnesium are heated with a burner flame, which ignits the magneisum and forms a grey-white solid. After cooling, the crucible and solid are reweighed and the date are analyzed to given an empirical formula of Mg_(5)O_(4) . Which could account for the observed Mg_(5)O_(4) results rather than the expected MgO ?

Ferrous oxide (FeO) crystal has a cubic structure and each edge of the unit cell is 5.0 A^(@) Taking density of the oxide as 4.0gcm^(-3) . The number of Fe^(2+) and O^(2-) ions present in each unit cell is:

MOTION-SOLID STATE-SOLVED OBJECTIVE
  1. The rank of a cubic unit cell is 4. The type of cell as- (A) Body cent...

    Text Solution

    |

  2. At room temperature, sodium crystallises in a body centred cubic cell ...

    Text Solution

    |

  3. A face-centred cubic solid of an element A has a largest sized guest a...

    Text Solution

    |

  4. An element A has BCC structure and another guest atom B, of largest po...

    Text Solution

    |

  5. An element A has a BCC structure and another guest atoms B, of largest...

    Text Solution

    |

  6. Calcium has face-centred cubic lattice and radius of calcium atom is 1...

    Text Solution

    |

  7. An atom crystallises in hexogonal closed pack arrangement. Determine d...

    Text Solution

    |

  8. A uniform cylindrical, polymer molecule crystallizes in body centred c...

    Text Solution

    |

  9. Show the following arrays of atoms on a plane in an atomic FCC.

    Text Solution

    |

  10. Cesium bromide crystallizes in cubic arrangement like CsCl. Given the ...

    Text Solution

    |

  11. Titanium metal crystallises in a BCC arrangement and radius of an atom...

    Text Solution

    |

  12. Copper metal crystallizes in face-centred cubic arrangement and surfac...

    Text Solution

    |

  13. Potassium crystallizes in "body centred cubic" arrangement and the sur...

    Text Solution

    |

  14. Magnesium oxide has the NaCl structure and radii of Mg^(2+) and O^(2–)...

    Text Solution

    |

  15. An unknown substance that uses gas at room temperature can be condense...

    Text Solution

    |

  16. Aluminium crystallizes in a cubic lattice with an edge of 404 pm and d...

    Text Solution

    |

  17. Except helium, all the noble gases crystallize with cubic close packed...

    Text Solution

    |

  18. All alkali metals crystallize into BCC strucutres. (a) Find an equatio...

    Text Solution

    |

  19. Some of the metals with BCC structures are not close packed. Therefore...

    Text Solution

    |

  20. How many unit cells of KBr are present in a 1.00 mm^(3) of KBr, KBr cr...

    Text Solution

    |