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CH2=CH underset(OH)underset(|)CHCH2CH2OH...

`CH_2=CH underset(OH)underset(|)CHCH_2CH_2OH overset(MnO_2)to A,` A is

A

`CH_2=CH_2underset(O)underset(||)C""CH_2CH_2OH`

B

`CH_2=CHunderset(OH)underset(|)C""CH_2CHO`

C

`CH_2=CHunderset(O)underset(||)C""CH_2CHO`

D

`CH_2=CHunderset(O)underset(||)C""CH_2underset(O)underset(||)(COH)`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the given question, we need to analyze the reaction of the compound with manganese dioxide (MnO2), which is a mild oxidizing agent. The compound in question is an allylic alcohol. Let's break down the steps to find the product A. ### Step-by-Step Solution: 1. **Identify the Structure of the Compound:** The compound given is: \[ CH_2=CH-CH(OH)-CH_2-CH_2OH \] This compound has two hydroxyl (OH) groups, making it a diol. 2. **Recognize the Type of Alcohol:** The alcohols present are: - One is an allylic alcohol (the one adjacent to the double bond). - The other is a primary alcohol (the one at the end of the chain). 3. **Understand the Reactivity with MnO2:** Manganese dioxide (MnO2) is known to selectively oxidize allylic and benzylic alcohols. In this case, the allylic alcohol will be oxidized to a carbonyl compound (ketone). 4. **Determine the Reaction Mechanism:** The allylic alcohol will undergo oxidation: - The hydroxyl group (OH) on the allylic carbon will be converted to a carbonyl group (C=O). - The structure after oxidation will be: \[ CH_2=CH-CO-CH_2-CH_2OH \] 5. **Identify the Product A:** The product A formed from the oxidation of the allylic alcohol is: \[ CH_2=CH-CO-CH_2-CH_2OH \] This compound contains a ketone functional group due to the oxidation of the allylic alcohol. 6. **Final Structure of Product A:** The final structure can be represented as: \[ CH_2=CH-CO-CH_2-CH_2OH \] This is the product A. ### Conclusion: The product A formed from the reaction of the given compound with MnO2 is: \[ A = CH_2=CH-CO-CH_2-CH_2OH \]
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MOTION-ALCOHOLS & ETHERS-EXERCISE -2 (LEVEL -I) OBJECTIVE PROBLEMS JEE MAIN
  1. overset(Alc.KOH)to Major product is -

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  2. A & B are

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  3. CH2=CH underset(OH)underset(|)CHCH2CH2OH overset(MnO2)to A, A is

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  4. What will be the chief productg from the following reaction sequence ?

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  5. Which of the following reagents cannot be used for the oxidation of 1^...

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  6. A water soluble C6H(14)O2 ompound is oxidized by lead tetraacetate (o...

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  7. A racemic mixture of (+-) 2-pheynl propanoic acid on esterification wi...

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  8. Which of the following alcohol can not be oxidized by KMnO4

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  9. Which of the following is wrong -

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  10. Which of the following reacts fastest with conc. HCl ?

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  11. Compare the rate of acid catalyst dehydration

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  12. Major product 'P' is :

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  13. CH3-overset(CH3)overset(|)underset(CH3)underset(|)C-CH2CH2CH2OH overse...

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  14. Identify the correct statement about reaction and products

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  15. overset(H^(oplus))underset(Delta)to Major product Major product is

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  16. Ph-overset(Ph)overset(|)underset(H)underset(|)C-overset(H)overset(|)un...

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  17. Compare the rate of dehydration of the following alcohols (I) Ph-under...

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  18. CH3-overset(CH3)overset(|)underset(OH)underset(|)C-overset(CH3)overset...

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  19. Incorrect statement is

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  20. Find out the product :

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