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Which of the following reactions is not ...

Which of the following reactions is not called Bouveault- Blanc reduction :

A

`R-CHO overset(Na+"ethanol")to R-CH_2OH`

B

`R-CO-R^'overset(Na+"ethanol")to R-CHOH-R^'`

C

`R-COOH overset(LiAlH_4)to R -CH_2OH`

D

`RCOOR^' overset(Na+"ethanol")to R-CH_2OH+R^'OH`

Text Solution

AI Generated Solution

The correct Answer is:
To determine which reaction is not called Bouveault-Blanc reduction, we need to understand what Bouveault-Blanc reduction entails. ### Step-by-Step Solution: 1. **Understanding Bouveault-Blanc Reduction**: - Bouveault-Blanc reduction is a method used to reduce carbonyl compounds (like aldehydes and ketones) to alcohols using sodium metal in the presence of ethanol (or other alcohols). 2. **Identifying the Reagents**: - The key reagent in Bouveault-Blanc reduction is sodium (Na) combined with ethanol (C2H5OH). This combination is crucial for the reduction process. 3. **Analyzing the Options**: - We need to look at the given options and identify which one does not involve sodium and ethanol as the reducing agents. - The options likely include various reducing agents such as lithium aluminum hydride (LiAlH4), sodium borohydride (NaBH4), and others. 4. **Recognizing the Non-Bouveault-Blanc Reduction**: - Lithium aluminum hydride (LiAlH4) is a strong reducing agent used for reducing esters, carboxylic acids, and other carbonyl compounds, but it is not part of the Bouveault-Blanc reduction process. - Therefore, if one of the options lists lithium aluminum hydride, that would be the correct answer. 5. **Conclusion**: - The reaction that is not called Bouveault-Blanc reduction is the one that involves lithium aluminum hydride (LiAlH4). ### Final Answer: The reaction that is not called Bouveault-Blanc reduction is the one involving **lithium aluminum hydride (LiAlH4)**. ---
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Knowledge Check

  • Which of the following reaction is called as 'Bouveault-Blanc reduction'

    A
    reduction of acyl halide through `Na//C_(2)H_(5)OH`
    B
    Reduction of ester through `Na//C_(2)H_(5)OH`
    C
    Reduction of anhydride through `Na//C_(2)H_(5)OH`
    D
    Reduction of carbonyl compounds through `Na//C_(2)H_(5)OH`
  • Which of the following reactions is an example of Bouveault Blanc reduction ?

    A
    `CH_(3)CN underset(C_(2)H_(5)OH)overset(Na)rarrCH_(3)CH_(2)NH_(2)`
    B
    `CH_(3)COCH_(3) underset(C_(2)H_(5)OH)overset(Na)rarr (CH_(3))_(2)CHOH`
    C
    `CH_(3)COCH_(3)overset(Ni//H_(2))rarr(CH_(3))_(2)CHOH`
    D
    `CH_(3)COCH_(3)underset("ether")overset(LiAlH_(4))rarr(CH_(3))_(2)CHOH`
  • The Bouveault-Blanc reduction involves

    A
    `C_(2)H_(5)OH//Na`
    B
    `LiAIH_(4)`
    C
    `C_(2)H_(5)MgX^(-)`
    D
    `Zn//HCl`
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