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underset ((X)) underset ("Optically acti...

`underset ((X)) underset ("Optically active") (C_5 CH_(13)N) underset (N_2)overset(NaNO_2//HCl) rarr (Y)underset (+" Other product" ) ("Tertiary alcohol")`
Find (X ) and (Y ) . Is (Y ) optically active ? Write the intermediate steps .

Text Solution

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The correct Answer is:
` X: C-underset(C ) underset(|)C-underset(NH_2)underset(|)C-C`
`Y : C-overset(OH)overset(|)underset( C) underset(|)C-C-C`
( Y is optically inactive )
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underset ((X)) underset ("Optically active") (C_5 CH_(13)N) underset (N_2)overset(NaNO_2//HCl) rarr (Y)underset (+" Other product" ) ("Tertiary alcohlo") Find (X ) and (Y ) . Is (Y ) optically active ? Write the intermediate steps .

underset("X (optically active)")(C_(5)H_(13)N)underset(-N_(2))overset(Aq.NaNO_(2)//HCl)to underset("tertiary alcohol+some other products")(Y) (i) Identify (X) and (Y) (ii) Is (Y) optically active? (iii) Give structures of intermediate(s), if any, in the formation of (Y) from (X)?

Knowledge Check

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  • Identify Y in the reaction, C_(6)H_(5)NH_(2) underset(273K)overset(NaNO_(2)//HCl)to X underset(dil." "H_(2)SO_(4))overset(H_(2)O)toY

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