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The standard potential of the following ...

The standard potential of the following cell is `0.23V` at `15^(@)C` and `0.21V` at `35^(@)C:`
`Pt|H_(2(g)|HCl(aq)|AgCl(s)|Ag(s)`
`a.` Write the cell reaction.
`b.` Calculate `DeltaH^(c-)` and `DeltaS^(c-)` for the cell reaction by assuming that these quantities remain unchanged in the range `15^(@)C` to `35^(@)C`
`c.` Calculate the solubility of `AgCl` in water at `25^(@)C`.
Given `:` The standard reduction potential of `Ag^(o+)(aq)|Ag(s)` is `0.80V` at `25^(@)C`.

Text Solution

Verified by Experts

The correct Answer is:
`/_\H^0=-49987 Jmol^(-1),/_\S^0=-96.5 Jmol^(-1)K^(-1),s=1.47 xx 10^(-5)`
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The standard potential of the following cell is 0.23 V at 15^(@)C and 0.21V at 35^(@)C . Pt|H_(2) |HCl(aq) |Agcl (s)|g(s) (i) write the cell reaction . (ii) Calculate DeltaH^(@) and DeltaS^(@) for the cell reaction by assuming that these quantities remain unchanged in the range 15^(@)C to 35^(@)C . (iii) calculate the solubility of AgCl in water at 25^(@)C . Give , the standard reduction potential of the (Ag^(+)(aq) //Ag(s) is 0.80 V at 25^(@) C .

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