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The electrochemical cell shown below is ...

The electrochemical cell shown below is a concentration cell. `M|M^(2+)(` saturated solution of sparingly soluble salt, `MX_(2))||M^(2+)(0.001 mol dm^(-3))|M`
The `emf` of the cell depends on the difference in the concentration of `M^(2+)` ions at the two electrodes. The `emf` of the cell at `298` is `0.059V`.
The solubility product `(K_(sp),mol^(3) dm^(-9))` of `MX_(2)` at 298 based on the information available the given concentration cell is `(` Take `2.303xxRxx298//F=0.059V)`

A

`1xx10^-15`

B

`4xx10^-15`

C

`1xx10^-12`

D

`4xx10^-12`

Text Solution

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The correct Answer is:
B
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The electrochemical cell shown below is a concentration cell M//M^(2+) (saturated solution of a sparingly soluble salt, MX_(2))||M^(2+)(0.001 mol dm^(-3))|M The emf of the cell depends on the difference in concentrations of Mn^(2+) ions at the two electrodes. The emf of the cell at 298 K is 0.059 V . The value of DeltaG ( kJ "mol"^(-1)) for the given cell is : (take 1 F = 96500 C "mol"^(-1) )

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