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{:("Column I","Column II"),("Alkyl—P—tol...

`{:("Column I","Column II"),("Alkyl—P—toluene sulfonate","Ethanolysis relative"),((A) CH_(3)— CH_(2)— OTs,(P) 10^(10)),((B) H_(2)C=CH-CH_(2)-OTs,(Q)10^(5)),((C) Ph-CH_(2)-OTs,(R)400),((D)Ph-underset(Ph)underset(|)(CH)-OTs,(R) 35),((E)Ph_(3)C-OTs.,(T)1):}`

Text Solution

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The correct Answer is:
`A to S ; B to R ; C to Q ; D to P`
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{:("Column I","Column II"),("Primary alkyl bromide","SN"_(2)"relative rate"),((A) CH_(3)— CH_(2)— Br,(P) 10^(-5)),((B) Me-CH_(2)-CH_(2)-Br,(Q)10^(-2)),((C)Me-underset(Me)underset(|)(CH)-CH_(2)-Br,(R) 0.8),((D)Me-underset(Me)underset(|)overset(Me)overset(|)(C)-CH_(2)-Br,(S)1):}

{:("column I"," ""Column II"),("Alkyl-bromide ","Relative rate of SN"^(1)),((A) CH_(3)-underset(CH_(3))underset(|)overset(CH_(3))overset(|)(C)-Br," "(P)1),((B) CH_(3)-underset(CH_(3))underset(|)(C)-Br," "(Q)11.6),((C)CH_(3)-CH_(2)-Br," "(R)1200000):}

Ph-underset(O)underset(||)C-CH_(3)overset(A)(to)Ph-CH_(2)-CH_(3) A could be :

CH_(3)-CH_(2)-CH_(2)-underset(OH)underset(|)(C )H-CH_(3) and CH_(3)-CH_(2)-underset(OH)underset(|)(C )H-CH_(2)-CH_(2)-CH_(3) are

Correct order of pK_(b) is (i) CH_(3)-CH_(2)-NH_(2) (ii) Ph-CH_(2)-NH_(2) (iii) H-underset(O)underset(||)(C)-NH-underset(O)underset(||)(C)-H (iv)

I.U.P.A.C name of H_(3)C-H_(2)C-HC=underset(CH_(3))underset(|)(C)-underset(CH_(3))underset(|)(HC)-CH_(2)-CH_(2)-CH_(3)

Write IUPAC names of the following compounds. (i) CH_(3)-CH_(2)-underset(CH_(3))underset(|)(C)=CH-CH_(3) (ii) CH_(3)-CH_(2)-CH_(2)-underset(C_(2)H_(5))underset(|)(CH)-CH_(2)-COOH

Write the product of following reactions (a) CH_3-CH_(2)-OH overset(I_(2)//KOH)to (b)Ph-CH_(2)-CO-CH_(3)overset(I_(2)//KOH)to (c) CH_(3)-underset(OH)underset(|)(CH)-Ph overset(I_(2)//KOH)to