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Acetophenone is prepared from :...

Acetophenone is prepared from `:`

A

Rosenmund reaction

B

Sandmeyer reaction

C

Wurtz reaction

D

Friedel craft reaction

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The correct Answer is:
To prepare acetophenone, we can utilize the Friedel-Crafts acylation reaction. Here’s a step-by-step breakdown of the process: ### Step-by-Step Solution: 1. **Identify the Reactants**: - We need benzene (C₆H₆) and acetyl chloride (CH₃COCl) as our starting materials. 2. **Use a Lewis Acid Catalyst**: - To facilitate the reaction, we will use anhydrous aluminum chloride (AlCl₃) as a catalyst. This is a Lewis acid that helps in the formation of an electrophile. 3. **Formation of the Electrophile**: - The acetyl chloride reacts with aluminum chloride to form an acetyl cation (CH₃C⁺O). This occurs as the AlCl₃ coordinates with the chlorine atom in acetyl chloride, making the carbonyl carbon more electrophilic. 4. **Electrophilic Attack**: - The electrophile (acetyl cation) then attacks the benzene ring. This is an electrophilic substitution reaction where the π electrons of the benzene ring attack the positively charged carbon of the acetyl cation. 5. **Formation of Acetophenone**: - This results in the formation of a resonance-stabilized carbocation intermediate. The intermediate then loses a proton (H⁺) to restore the aromaticity of the benzene ring, resulting in the formation of acetophenone (C₆H₅COCH₃). 6. **Final Product**: - The final product of this reaction is acetophenone, which is represented as C₆H₅COCH₃. ### Summary: The preparation of acetophenone involves the Friedel-Crafts acylation of benzene with acetyl chloride in the presence of anhydrous aluminum chloride as a catalyst.
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