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Acetone overset( HCN) ( rarr) ( A) overs...

Acetone `overset( HCN) ( rarr) ( A) overset( H_(3) O^(+))(rarr) ( B ) `. In the above sequence of reaction A and B are `:`

A

`( CH_(3))_(2) C( OH ) CN, ( CH_(3))_(2)C( OH ) COOH`

B

`( CH_(3))_(2)C(OH) CN, ( CH_(3))_(2)C ( OH)_(2)`

C

`( CH_(3))_(2)C(OH)CN,(CH_(3))_(2)CHCOOH`

D

`(CH_(3))_(2)C(OH)CN, ( CH_(3))_(2)C=O`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we need to identify the products A and B from the given reaction sequence involving acetone and HCN followed by hydrolysis. ### Step-by-Step Solution: 1. **Identify the Reactants**: The starting compound is acetone, which has the structure CH₃COCH₃. 2. **Reaction with HCN**: When acetone reacts with HCN, the cyanide ion (CN⁻) acts as a nucleophile and attacks the carbonyl carbon of acetone. This leads to the formation of a cyanohydrin. **Product A**: The product formed after the reaction with HCN is 2-hydroxy-2-methylpropanenitrile (or simply acetone cyanohydrin), which can be represented as: \[ \text{A: } CH_3C(OH)(CN)CH_3 \] 3. **Hydrolysis of Product A**: The next step involves the hydrolysis of the cyanohydrin (Product A) in the presence of an acid (H₃O⁺). During hydrolysis, the nitrile group (CN) is converted to a carboxylic acid (COOH). The hydrolysis mechanism involves: - Protonation of the hydroxyl group. - Nucleophilic attack by water on the carbon atom. - Rearrangement leading to the formation of a carboxylic acid. **Product B**: The final product after hydrolysis is 2-hydroxy-2-methylpropanoic acid (or simply lactic acid), which can be represented as: \[ \text{B: } CH_3C(OH)COOH \] ### Final Answer: - **A**: Acetone cyanohydrin (CH₃C(OH)(CN)CH₃) - **B**: Lactic acid (CH₃C(OH)COOH) ---
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