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Give the characteristic tests for the fo...

Give the characteristic tests for the following gases : (a) `CO_(2)` (b) `SO_(2)` (c) `O_(2)` (d) `H_(2)`

Text Solution

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(a) Test for `CO_(2)` gas (lime water test ) When `CO_(2)` gas is passed through lime water, it turns milky due to the formation of insoluble calcium carbonate.
`underset(underset("(colourless)")("Lime water"))(Ca(OH)_(2)(aq))+underset(underset("dioxide")("Carbon"))(CO_(2))to underset(underset(underset("(white)")("carbonate"))("Carbon"))(CaCO_(3)(s))+underset("Water")(H_(2)O)`
If the gas is in excess, milkiness disappears due to the formation of soluble calcium bicarbonate.
`underset(underset("dioxide")("Carbon"))(CO_(2))+underset("Water")(H_(2)O)+underset(underset("carbonare")("Calcium"))(CaCO_(3))to underset(underset(underset("(soluble)")("bicarbonate"))("Calcium"))(Ca(HCO_(3))_(2))`
(b) Test for `SO_(2)` gas
(i) Sulphur dioxide gas turns moist litmus papar blue to red because `SO_(2)` is acidic in nature.
(ii) Sulphur dioxide gas turns acidified potassium dichromate (vi) solution from orange to green.
`underset(underset("dichromate")("Potassium"))(K_(2)Cr_(2)O_(7))+3SO_(2)+H_(2)SO_(4)to underset(underset("sulphate")("Chromium"))(Cr_(2)(SO_(4))_(3))+K_(2)SO_(4)+H_(2)O`
(c) Test for `O_(2)` gas When a wooden splinter is brought near the mouth of the gas jar containing oxygen gas, it burns brightly as oxygen is the supporter of combustion.
`underset("Wood")(C)+underset("Oxgen")(O_(2))to underset(underset("dioxide")("Carbon"))(CO_(2))+"Heat +Light"`
(d) Test for `H_(2)` gas Hydrogen gas burns in the presence of air or oxygen with a pop sound when a burning candle is brought near it.
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Knowledge Check

  • Which of the following are green house gases ? (a) CO_2 (b) O_2 (c) O_3 (d) CFC (e) H_2O

    A
    a,b,d
    B
    a,b,c,d
    C
    a,c,d
    D
    a,c,d,e
  • The increasing order of nucleophilicity of the following nucleophiles is: (a) CH_(3)CO_(2)^(-) (b) H_(2)O (c) CH_(3)SO_(3)^(-) (d) overset(O)H

    A
    `(b) lt (c) lt (d) lt (a)`
    B
    `(d) lt (a) lt (c) lt (b)`
    C
    `(b) lt (c) lt (a) lt (d)`
    D
    `(a) lt (d) lt (c) lt (b)`
  • In which of the following compounds resonance does not occurs (a) H_2O (b) SiO_2 (c ) SO_2 (d) CO_2

    A
    a and d
    B
    a and b
    C
    c and d
    D
    b, c and d
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