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In solid state, PCl(5) is a…….....

In solid state, `PCl_(5)` is a……..

A

convalent solid

B

octahedral structure

C

ionic solid with `[PCl_(6)]^(+)` octahedral and `[PCl_(4)]^(-)` tetrahedral

D

ionic solid with `[PCl_(4)]^(+)` tetrahedral and `[PCl_(6)]^(-)` octahedral

Text Solution

Verified by Experts

The correct Answer is:
D

In solid state `PCl_(5)` exists as an ionic solid with `[PCl_(4)]^(+)` tetrahedral and `[PCl_(6)]^(-)` octahedral.
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NCERT EXEMPLAR-P-BLOCK ELEMENTS-P-Block Elements
  1. A black compound of manganese reacts with a halogen acid to give green...

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  2. In the preparation of compounds of Xe, Bartlett has taken O(2)^(+)Pt F...

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  3. In solid state, PCl(5) is a……..

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  4. Reduction potentials of some ions are given below. Arrange them in dec...

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  5. Which of the following is isoelectronic pair ?

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  6. If chlorine gas is passed through hot NaOH solution, two changes are o...

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  7. Which of the following options are not accordance with the property me...

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  8. Which of the following is correct for P(4) molecule of white phosphoru...

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  9. Which of the following statements are correct? I. Among halogens, ra...

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  10. Which of the following statements are correct for SO(2) gas? (a) I...

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  11. Which of the following statements are correct ? (a) All the three...

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  12. Which of the following orders are correct as per the properties mentio...

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  13. Which of the following statements are correct? (a) SS bond is prese...

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  14. In which of the following reactions conc. H(2)SO(4) is used as an ox...

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  15. Which of the following statements are true? (a) Only type of intera...

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  16. In the preparation of H(2)SO(4) by Contact process, why is SO(3) not ...

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  17. Write a balanced chemical equation for the reaction showing catalytic ...

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  18. Write the structure of pyrophosphoric acid.

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  19. PH(3) forms bubbles when passed slowly in water but NH(3) dissolves. E...

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  20. In PCl(5) phosphorus is in sp^(3) d hybridised state but all its five ...

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