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The source of nitrogen in Gabriel synthe...

The source of nitrogen in Gabriel syntheisis of amine is..

A

sodium azide, `NaN_(3)`

B

sodium nitrite, `NaNO_(2)`

C

potassium cyanide, KCN

D

potassium pthalimide `C_(6)H_(4)(CO)_(2)N^(-)K^(+)`

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### Step-by-Step Solution: 1. **Understanding Gabriel Synthesis**: Gabriel Synthesis is a method used to synthesize primary amines. It involves the use of phthalimide as a starting material. 2. **Starting Material**: The reaction begins with phthalimide, which has the structure of a cyclic imide. The nitrogen in phthalimide is part of the imide functional group. 3. **Formation of Potassium Salt**: When phthalimide reacts with potassium hydroxide (KOH), it forms the potassium salt of phthalimide. This step is crucial as it prepares the compound for further reaction with alkyl halides. 4. **Reaction with Alkyl Halide**: The potassium salt of phthalimide then reacts with an alkyl halide (R-X) to form N-alkyl phthalimide. This step introduces the alkyl group into the nitrogen atom. 5. **Hydrolysis**: The N-alkyl phthalimide undergoes alkaline hydrolysis, which involves the addition of water in the presence of a base. This reaction yields a primary amine (RNH2) and phthalic acid. 6. **Source of Nitrogen**: The nitrogen atom in the final primary amine product comes from the original phthalimide used in the synthesis. Thus, the source of nitrogen in Gabriel Synthesis is phthalimide. ### Final Answer: The source of nitrogen in Gabriel synthesis of amine is phthalimide. ---

### Step-by-Step Solution: 1. **Understanding Gabriel Synthesis**: Gabriel Synthesis is a method used to synthesize primary amines. It involves the use of phthalimide as a starting material. 2. **Starting Material**: The reaction begins with phthalimide, which has the structure of a cyclic imide. The nitrogen in phthalimide is part of the imide functional group. ...
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