Home
Class 12
CHEMISTRY
A primary amine, RNH(2) can be reacted w...

A primary amine, `RNH_(2)` can be reacted with `CH_(3)-X` to get secondary amine, `R-NHCH(3)`, but the only disadvantage is that `3^(@)` amine and quaternary ammonium salts are also obtained as side products. Can your suggest a method where `RNH_(2)` forms only `2^(@)` amine?

Text Solution

Verified by Experts

`underset("Primary amine")(RNH_(2)) underset("Carbylamine reaction Alkyl to iso cyanide")overset(KOH//CHCl_(3))to underset("Alkyl iso cyanide")(RNC) overset(H_(2)//Pd)to underset("Secondary amine")(RNHCH_(3))`
Primary amines show carbylamine reaction in which two H-atoms attached to N-atoms of `NH_(2)` are replaced by one C-atom. On catalystic reduction, isocyanide (formed) produces secondary amine and not tetiary or quaternary salts.
Promotional Banner

Topper's Solved these Questions

  • ALDEHYDE, KETONES AND CARBOXYLIC ACIDS

    NCERT EXEMPLAR|Exercise Aldehyde, Ketones And Carboxylic Acids|50 Videos
  • BIOMOLECULES

    NCERT EXEMPLAR|Exercise Biomolecules|71 Videos

Similar Questions

Explore conceptually related problems

How many molecules of CH_(3) I combines with one molecule of methyl amine to give quaternary ammonium salt ?

Amines are derivatives of ammonia and are classified as 1^(@), 2^(@) , and 3^(@) , Primary and secondary (but not teritiary amines) form intermolecular hydrogen bonds and thus they boil at highter temperatures than expected. Like ammonia, all amines are basic, although they differ in their basic nature. As amines are considered as derivatives of ammonia, quaternary ammonium salts are considered as derivatives of ammonium salts. Only the quaternary ammonium salts can shown optical activity. Which of the following statement is correct ?

NCERT EXEMPLAR-AMINES-Amines
  1. Write down the IUPAC name of

    Text Solution

    |

  2. A compound Z with molecular formula C(3)H(9)N reacts with C(6)H(5)SO(2...

    Text Solution

    |

  3. A primary amine, RNH(2) can be reacted with CH(3)-X to get secondary a...

    Text Solution

    |

  4. Complete the following reaction

    Text Solution

    |

  5. Why is aniline soluble in aqueous HCl?

    Text Solution

    |

  6. Suggest a route by which of the following conversion can be accomplish...

    Text Solution

    |

  7. Identfy A and B in the following reactions.

    Text Solution

    |

  8. How will you carry out the follwing conversion? (i) Toluene -p-tolui...

    Text Solution

    |

  9. Write following conversions (i) Nitrobenzene-Acetanilide (ii) Acet...

    Text Solution

    |

  10. A solution contains 1g mol. Each of p-toluene diazonium chloride and p...

    Text Solution

    |

  11. How will you bring out the following conversion?

    Text Solution

    |

  12. How will you carry out the following conversion?

    Text Solution

    |

  13. How will you carry out the following conversion?

    Text Solution

    |

  14. How will you carry out the following conversion?

    Text Solution

    |

  15. Match the reactions given in Column I with the statements given in Col...

    Text Solution

    |

  16. Match the reactions given in Column I with the statements given in Col...

    Text Solution

    |

  17. Assertion(A) Acylation of amines gives a monsubstituted product where...

    Text Solution

    |

  18. Assertion (A): Hofmann's bromamide reaction is given by primary amines...

    Text Solution

    |

  19. Assertion (A): N-ethylbenzene sulphonamide is solube in alkali. Reas...

    Text Solution

    |

  20. Assertion(A): N,N-diethylbenzene sulphonamide is insoluble in alkali. ...

    Text Solution

    |