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Assertion(A): N,N-diethylbenzene sulphon...

Assertion(A): N,N-diethylbenzene sulphonamide is insoluble in alkali.
Reason(R ): Sulphonyl group attached to nitrogen atoms is strong electron withdrawing group.

A

Both assertion and reason are worng

B

Both assertion and reason are correct statement but reason is not correct explaination of assertion.

C

Assertion is correct statements and reason is correct explanation of assertion.

D

Both asseration and reason are correct statements and reason is correct explanation of assertion .

Text Solution

AI Generated Solution

To analyze the given assertion and reason, we will break down the statements and provide a step-by-step solution. ### Step 1: Understanding the Assertion **Assertion (A)** states that N,N-diethylbenzene sulphonamide is insoluble in alkali. - **Structure Analysis**: N,N-diethylbenzene sulphonamide consists of a benzene ring attached to a sulphonamide group (SO2NH) with two ethyl groups attached to the nitrogen atom. - **Solubility in Alkali**: For a compound to be soluble in alkali, it typically needs to have acidic hydrogens that can react with hydroxide ions (OH-) to form soluble anions. In the case of N,N-diethylbenzene sulphonamide, there are no acidic hydrogens present on the nitrogen that can react with alkali. Therefore, it does not form any soluble species in alkaline conditions. ...
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NCERT EXEMPLAR-AMINES-Amines
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  2. How will you carry out the follwing conversion? (i) Toluene -p-tolui...

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  3. Write following conversions (i) Nitrobenzene-Acetanilide (ii) Acet...

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  4. A solution contains 1g mol. Each of p-toluene diazonium chloride and p...

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  5. How will you bring out the following conversion?

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  6. How will you carry out the following conversion?

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  7. How will you carry out the following conversion?

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  8. How will you carry out the following conversion?

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  9. Match the reactions given in Column I with the statements given in Col...

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  10. Match the reactions given in Column I with the statements given in Col...

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  11. Assertion(A) Acylation of amines gives a monsubstituted product where...

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  12. Assertion (A): Hofmann's bromamide reaction is given by primary amines...

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  13. Assertion (A): N-ethylbenzene sulphonamide is solube in alkali. Reas...

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  14. Assertion(A): N,N-diethylbenzene sulphonamide is insoluble in alkali. ...

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  15. Assertion(A): Only a small amount of HCl is required in the reduction ...

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  16. Assertion(A): Aromatic 1^(@ amines can be prepared by Gabriel phtalmi...

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  17. Assertion(A): Acetanilide is less basic aniline. Reson(R ): Acetylat...

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  18. A hydrocarbon 'A' (C(4)H(8)) on reaction HCl gives a compound 'B', (C(...

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  19. A colours substance 'A' (C(6)H(7)) is sparingly soluble in water and g...

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  20. Predict the reagent or the product in the following reaction sequence.

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