Home
Class 12
CHEMISTRY
Assertion(A): Acetanilide is less basic ...

Assertion(A): Acetanilide is less basic aniline.
Reson(R ): Acetylation of aniline results in decrease of electron density on nitrogen.

A

Both assertio and reason are worng

B

Both assertion and reason are correct statement but reason is not correct explaination of assertion.

C

Assertion is correct statements and reason is correct explanation of assertion.

D

Both asseration and reason are correct statements and reason is correct explanation of assertion .

Text Solution

AI Generated Solution

To solve the question regarding the assertion and reason about the basicity of acetanilide compared to aniline, we can break it down into the following steps: ### Step 1: Understand the Structures - **Aniline** is an aromatic amine with the formula C6H5NH2. It has an amino group (-NH2) attached to a benzene ring. - **Acetanilide** is derived from aniline by acetylation, which involves adding an acetyl group (–COCH3) to the amino group, resulting in the structure C6H5NH(COCH3). ### Step 2: Analyze Basicity - Basicity in amines is largely determined by the availability of the lone pair of electrons on the nitrogen atom. The more electron density on the nitrogen, the more basic the compound is. ...
Promotional Banner

Topper's Solved these Questions

  • ALDEHYDE, KETONES AND CARBOXYLIC ACIDS

    NCERT EXEMPLAR|Exercise Aldehyde, Ketones And Carboxylic Acids|50 Videos
  • BIOMOLECULES

    NCERT EXEMPLAR|Exercise Biomolecules|71 Videos

Similar Questions

Explore conceptually related problems

Acetanilide is less basic than aniline.

A: Nitration of aniline can only be done by protecting -NH_2 group through acetylation. R: Acetylation of aniline results in the increase of electron density on the benzene ring.

Assertion: Aniline is less basic than acetamide Reason: Lone pair of N is involved in resonance

Aniline is less/more basic than ethylamine.

Assertion: Benzylamine is more basic than aniline. Reason: NH_2 group is electron releasing group

Assertion : Acid amides are weakly basic in nature. Reason : Basic character of acid amides is due to lone electron pair on nitrogen atom.

NCERT EXEMPLAR-AMINES-Amines
  1. Identfy A and B in the following reactions.

    Text Solution

    |

  2. How will you carry out the follwing conversion? (i) Toluene -p-tolui...

    Text Solution

    |

  3. Write following conversions (i) Nitrobenzene-Acetanilide (ii) Acet...

    Text Solution

    |

  4. A solution contains 1g mol. Each of p-toluene diazonium chloride and p...

    Text Solution

    |

  5. How will you bring out the following conversion?

    Text Solution

    |

  6. How will you carry out the following conversion?

    Text Solution

    |

  7. How will you carry out the following conversion?

    Text Solution

    |

  8. How will you carry out the following conversion?

    Text Solution

    |

  9. Match the reactions given in Column I with the statements given in Col...

    Text Solution

    |

  10. Match the reactions given in Column I with the statements given in Col...

    Text Solution

    |

  11. Assertion(A) Acylation of amines gives a monsubstituted product where...

    Text Solution

    |

  12. Assertion (A): Hofmann's bromamide reaction is given by primary amines...

    Text Solution

    |

  13. Assertion (A): N-ethylbenzene sulphonamide is solube in alkali. Reas...

    Text Solution

    |

  14. Assertion(A): N,N-diethylbenzene sulphonamide is insoluble in alkali. ...

    Text Solution

    |

  15. Assertion(A): Only a small amount of HCl is required in the reduction ...

    Text Solution

    |

  16. Assertion(A): Aromatic 1^(@ amines can be prepared by Gabriel phtalmi...

    Text Solution

    |

  17. Assertion(A): Acetanilide is less basic aniline. Reson(R ): Acetylat...

    Text Solution

    |

  18. A hydrocarbon 'A' (C(4)H(8)) on reaction HCl gives a compound 'B', (C(...

    Text Solution

    |

  19. A colours substance 'A' (C(6)H(7)) is sparingly soluble in water and g...

    Text Solution

    |

  20. Predict the reagent or the product in the following reaction sequence.

    Text Solution

    |