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Why a solution of [Ni(CN)4]^(2-) is colo...

Why a solution of `[Ni(CN)_4]^(2-)` is colourless?

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A solution of [Ni(H_(2)O)_(6)]^(2+) is green but a solution of [Ni(CN)_(4)]^(2-) is colourless Explain.

STATEMENT -1 A solution of [Ni(H_(2)O)_(6)]^(2+) is geen but a solution of [Ni(CN)_(4)]^(2-) is colourless. STATEMENT-2 : : Energy difference between d level ( i.e.Delta )for H_(2)O complex (paramagnetic) is in the visible region and that for the cyano complex (diamagnetic)is in the UV region.

Assertion A solution of [Ni(H_(2)O)_(6)]^(2+) is green but a solution of [Ni(CN)_(4)]^(2+) is colourless Reason [Ni(CN)_(4)]^(2+) is square planar complex .

(i) What type of isomerism is shown by the complex [Co(NH_(3))_(6)] [Cr(CN)_(6))] ? (ii) Why a solution of [Ni(H_(2)O)_(6)^(2+) is given while a solution of [No(CN)_(4)]^(2-) colourless ? (At. No. of Ni = 28) (iii) Write the IUPAC name of the following complex : [Co(NH_(3))_(5) (CO_(3))] Cl

Why solution of \([Ni(H_{2}O)_{6})]^{2+}\) is green while solution of \([Ni(H_{2}O)_{4})]^{-}\) is colourless. [at no of Ni=28]

CBSE COMPLEMENTARY MATERIAL-PRACTICE PAPER 3-Section C
  1. Write hybridisation and magnetic behaviour of the complex [Ni(CO)(4)].

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  2. Which of the following is more stable complex and why? [CO(NH3)6]^(3+...

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  3. A Co-ordination compound CrCl3.6H2O is mixed with AgNO3, 2 moles of Ag...

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  4. Why a solution of [Ni(CN)4]^(2-) is colourless?

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  5. Identify A in the following reactions : (C6H5CH2)2 Cd + 2CH3COCl to ...

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  6. (A), (B) and (C ) are three non-cylic funtional isomers of a carbonyl ...

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  7. (a) Prepare benzoic acid from Ethylbenzene. (c) Why pka" of "F-CH2- ...

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  8. Calculate the e.m.f. of the following cell at 298K: 2Cr(s)+3Fe^(2+)(...

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  9. Why conductivity of electrolyte decreases with decreases in concentrat...

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  10. State Faraday's first law of electrolysis.

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  11. Define limiting molar conductivity.

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  12. Ecell for the given redox reaction is 2.71 V Mg(s) + Cu^(2+)(0,01M) to...

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  13. Draw structure of (i) XeOF4" (ii) "HClO3

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  14. Account for the following (i) Fluorine forms only one oxoacid HOF ...

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  15. Arrange in increasing order of boiling point H2O, H2S, H2Se, H2Te

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  16. What are the conditions to maximise yield of H2SO4 in contact process

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  17. F2 has lower bond dissociation enthalpy than Cl2. Why?

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  18. Complete the equation XeF2 + PF5 to

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  19. There is large difference in boiling point of oxygen and sulphur. Give...

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  20. Ozone is thermo dynamically unstable. Explain

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