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The number of unbranched isomers (includ...

The number of unbranched isomers (including stereoisomers) of `C_(6)H_(12)` are

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To find the number of unbranched isomers (including stereoisomers) of \( C_6H_{12} \), we need to consider the structural possibilities for hexene, which is the alkene formed from hexane by introducing a double bond. ### Step-by-Step Solution: 1. **Identify the Molecular Formula**: The molecular formula \( C_6H_{12} \) indicates that we are dealing with an alkene (since it has one double bond). 2. **Determine the Structure**: The simplest structure for \( C_6H_{12} \) is hexene, which can be represented as follows: - Straight-chain structure: \( CH_3-CH_2-CH_2-CH_2-CH=CH_2 \) 3. **Identify Possible Positions for the Double Bond**: For hexene, the double bond can be located at different positions: - 1-hexene: \( CH_3-CH_2-CH_2-CH_2-CH=CH_2 \) - 2-hexene: \( CH_3-CH_2-CH=CH-CH_2-CH_3 \) - 3-hexene: \( CH_3-CH=CH-CH_2-CH_2-CH_3 \) 4. **Consider Stereoisomers**: - **2-hexene** can exhibit geometric (cis/trans) isomerism because the double bond is between two different groups: - **Cis-2-hexene**: Both methyl groups on the same side. - **Trans-2-hexene**: Methyl groups on opposite sides. - **1-hexene** and **3-hexene** do not have stereoisomers since they do not have two different groups attached to the carbons involved in the double bond. 5. **Count the Isomers**: - 1-hexene: 1 isomer - 2-hexene: 2 isomers (cis and trans) - 3-hexene: 1 isomer - Total = 1 (from 1-hexene) + 2 (from 2-hexene) + 1 (from 3-hexene) = 4 isomers. ### Final Answer: The total number of unbranched isomers (including stereoisomers) of \( C_6H_{12} \) is **4**.
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