Home
Class 12
CHEMISTRY
Consider the following sequence of react...

Consider the following sequence of reactions
`underset((C_(4)H_(8)O_(3)))(A overset(CrO_(3))rarr B) overset("Warm")rarr CH_(3)overset(O) overset(||)C CH_(3)+CO_(2)`
The compound (A) is :

A

`HOCH_(2)CH_(2)CH_(2)COOH`

B

`CH_(3)CH(OH)CH_(2)COOH`

C

`CH_(3)CH_(2)CH(OH)COOH`

D

`(CH_(3))_(2)C(OH)COOH`

Text Solution

AI Generated Solution

The correct Answer is:
To determine the compound (A) with the formula C₄H₈O₃, we need to analyze the sequence of reactions provided. ### Step-by-Step Solution: 1. **Identify the Reaction Type**: The first reaction involves the treatment of compound A (C₄H₈O₃) with CrO₃, which is a mild oxidizing agent. The second part of the reaction indicates that upon warming, a product (B) is formed that leads to the release of CO₂ gas. **Hint**: Recognize that the release of CO₂ suggests decarboxylation, which typically occurs with carboxylic acids. 2. **Analyze Product B**: The product B, after warming, is indicated to be CH₃C(=O)CH₃ (acetone) plus CO₂. This suggests that B must contain a carboxylic acid group that can lose CO₂ upon heating. **Hint**: The presence of CO₂ upon heating indicates that B likely has a carboxylic acid functional group. 3. **Determine Structure of B**: Given that B leads to CH₃C(=O)CH₃ (acetone) after decarboxylation, we can deduce that B must be a carboxylic acid with the structure CH₃C(=O)CH₂COOH (butanoic acid). This structure allows for the loss of CO₂ when heated. **Hint**: Consider the structure of B and how it can decarboxylate to yield acetone and CO₂. 4. **Identify Compound A**: Since B is derived from A through oxidation, and B is a carboxylic acid, A must be a secondary alcohol that can be oxidized to form B. The structure of A can be deduced as CH₃CH(OH)CH₂COOH (2-hydroxybutanoic acid). **Hint**: Remember that secondary alcohols oxidize to ketones, and since B is a carboxylic acid, A must be a secondary alcohol that can form a carboxylic acid upon oxidation. 5. **Final Structure of A**: The final structure of A is CH₃CH(OH)CH₂COOH, which is 2-hydroxybutanoic acid. ### Conclusion: The compound (A) is 2-hydroxybutanoic acid (C₄H₈O₃).
Promotional Banner

Topper's Solved these Questions

  • NTA JEE MOCK TEST 35

    NTA MOCK TESTS|Exercise CHEMISTRY|25 Videos
  • NTA JEE MOCK TEST 37

    NTA MOCK TESTS|Exercise CHEMISTRY|25 Videos

Similar Questions

Explore conceptually related problems

Consider the following sequence of reactions C_(2)H_(5)C -= CH overset(CH_(3)MgBr)rarr A underset((2)H_(2)O^(+))overset((1)HCHO) rarr B The product (B) is

In the following sequence of reactions: CH_(3)-Br overset(KCN)rarr A overset(H_(3)overset(+)(O))rarr B overset(LiAlH_(4))rarr C the end product (C ) is :

The product (D) in the following sequence of reactions is : C_(2)H_(4)overset(HBr)(rarr)(A)overset(NaOH(aq.))(rarr)(B) overset(Na)(rarr)(C ) overset(CH_(3)I)(rarr)

In the following sequence of reaction, the product C is CH_(3)-Br overset(KCN) rarr A overset(H_(2)O^(+))rarr B overset(LiAlH_(4))underset("Ether")rarr C

Consider the following sequence of reactions. C_(6)H_(6) + CH_(3) CH = CH_(2) underset("heat")overset(H_(3)PO_(4))rarrA underset(2. H_(3)O^(+))overset(1. O_(2), "heat")rarr B + C The products (B) and (C) are:

In the following sequence of reaction, the end product is : HC-=CHoverset(Hg^(2+)//H_(2)SO_(4))rarr(A) overset(CH_(3)MgX)underset([H_(2)O])rarr(B)overset([O])rarr(C)

Consider the following sequence of reaction: HO-overset(O)overset(||)(C)-underset(CH_(3))underset(|)overset(CH_(3))overset(|)(C)-C-=N overset(200^(@)C)rarr A overset(LiAIH_(4))underset(H_(2)O)rarrB,(B) is:

What is the given reaction known as ? CH_(3)-overset(O)overset(||)C-CH_(3)overset(C_(6)H_(5)CO_(3)H)rarr CH_(3)-overset(O)overset(||)C-O-CH_(3)

Consider the following reaction (A)overset((i)O_3)underset((ii)H_2"O"//Zn)rarrCH_3-overset(O)overset(||)C-CH_2-overset(O)overset(||)C-CH_2-overset(O)overset(||)C-CH_3+3HCHO Compound 'A' will be

NTA MOCK TESTS-NTA JEE MOCK TEST 36-CHEMISTRY
  1. For [FeF(6)]^(3-) and [CoF(6)]^(3-), the correct statement is

    Text Solution

    |

  2. Consider the following structures (I), (II), (III) and (IV). Whic...

    Text Solution

    |

  3. Which of the following statements is incorrect?

    Text Solution

    |

  4. Which one of the following is most acidic ?

    Text Solution

    |

  5. Which of the following volatile?

    Text Solution

    |

  6. Which of the following alkanes will give a single product with a methy...

    Text Solution

    |

  7. Which of the following can possibly be used as analgesic without causi...

    Text Solution

    |

  8. Consider the following sequence of reactions underset((C(4)H(8)O(3))...

    Text Solution

    |

  9. 1, 1- Dichloropropane on hydrolysis gives :

    Text Solution

    |

  10. The maximum probability of finding electron in the d(xy) orbital is -

    Text Solution

    |

  11. The emf of the cell, Zn|Zn^(2+) (0.01 M)||Fe^(2+) (0.001 M)|Fe at 29...

    Text Solution

    |

  12. In the mixture of (NaHCO(3)+Na(2)CO(3)) volume of HCl required is x mL...

    Text Solution

    |

  13. A complex is represented as CoCl(3) . XNH(3). Its 0.1 molal solution i...

    Text Solution

    |

  14. The shortest distance between two Na^(+) ions in rock - salt arrangeme...

    Text Solution

    |

  15. The number of stereoisomers obtained by bromination of trans-2-butene ...

    Text Solution

    |

  16. Two moles of an ideal monoatomic gas at 5 bar and 300 K are expanded i...

    Text Solution

    |

  17. The pH at the equivalent point for the titration of 0.10 M KH(2)BO(3) ...

    Text Solution

    |

  18. Initially 3 moles of 'A' was taken in a 1 L container. The approx. mol...

    Text Solution

    |

  19. 0.15g of a subatance dissolved in 15g of solvent boiled at a temperatu...

    Text Solution

    |

  20. What hydrogen-like ion has the wavelength difference between the first...

    Text Solution

    |