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CH(3)-CH(2)-N=O and CH(3)-CH=N-OH are:...

`CH_(3)-CH_(2)-N=O and CH_(3)-CH=N-OH` are:

A

Functional group isomer

B

Tautomer

C

Position isomer

D

Not an isomer

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AI Generated Solution

The correct Answer is:
To determine the relationship between the compounds \( CH_3-CH_2-N=O \) and \( CH_3-CH=N-OH \), we need to analyze their structures and identify if they are tautomers. ### Step 1: Identify the Structures - The first compound \( CH_3-CH_2-N=O \) can be recognized as an oxime derivative where nitrogen is bonded to an oxygen with a double bond. - The second compound \( CH_3-CH=N-OH \) is an oxime as well, where nitrogen is bonded to a hydroxyl group. ### Step 2: Analyze the Functional Groups - In the first compound, the nitrogen is in a +1 oxidation state due to the double bond with oxygen. - In the second compound, nitrogen is bonded to a hydroxyl group, which indicates a different oxidation state and functional group arrangement. ### Step 3: Determine Tautomerism - Tautomerism is a type of isomerism where isomers (tautomers) readily interconvert, typically involving the relocation of a hydrogen atom and a shift in bonding. - In this case, the hydrogen atom can shift from the nitrogen in the first compound to the nitrogen in the second compound, leading to the formation of the other compound. ### Step 4: Conclusion - Since both compounds can interconvert through the transfer of a hydrogen atom, they are classified as tautomers. Thus, the answer to the question is that \( CH_3-CH_2-N=O \) and \( CH_3-CH=N-OH \) are **tautomers**.
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