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The number of possible sterio isomers in...

The number of possible sterio isomers in `Ma_(3)b_(3)` is equal to
(Here a, b are different monodentate ligands).

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To determine the number of possible stereoisomers for the complex \( MA_3B_3 \), where \( A \) and \( B \) are different monodentate ligands, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Type of Complex**: The complex \( MA_3B_3 \) is an octahedral complex because it has a coordination number of 6 (3 ligands of type A and 3 ligands of type B). **Hint**: Remember that octahedral complexes have a coordination number of 6. 2. **Determine the Possible Geometrical Isomers**: In octahedral complexes with two different types of ligands, we can have two types of geometrical isomers: - **Facial (fac)**: where the same type of ligands occupy adjacent positions. - **Meridional (mer)**: where the same type of ligands occupy positions that are opposite each other. **Hint**: Visualize the arrangement of ligands in octahedral geometry to distinguish between facial and meridional isomers. 3. **Draw the Geometrical Isomers**: - For the **fac** isomer, the three A ligands will be on one face of the octahedron, and the three B ligands will be on the opposite face. - For the **mer** isomer, the three A ligands will occupy one plane of the octahedron, and the three B ligands will be in the opposite plane. **Hint**: Sketch the octahedron and label the positions of ligands A and B to visualize the arrangements. 4. **Check for Optical Isomers**: Next, we need to check if these geometrical isomers can exhibit optical isomerism. Optical isomers are non-superimposable mirror images. - For both the fac and mer isomers, there is a plane of symmetry present. This means that they cannot have optical isomers. **Hint**: Look for planes of symmetry in your drawings to determine if optical isomers are possible. 5. **Count the Total Number of Stereoisomers**: Since we have identified 2 geometrical isomers (fac and mer) and no optical isomers, the total number of stereoisomers for the complex \( MA_3B_3 \) is 2. **Hint**: Sum the number of geometrical isomers and optical isomers to find the total. ### Final Answer: The number of possible stereoisomers in \( MA_3B_3 \) is **2** (both geometrical isomers: fac and mer).
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