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The specific conductance of a 0.1 N KCI ...

The specific conductance of a 0.1 N KCI solution at `25^@ C` is 0.015 `ohm^ (-1) cm^(-1)`. The resistances of the cell containing the solution at the same temperature was found to be 60 Omega`. The cell constant `(in cm^(-1))` will be

A

0.9

B

`4 xx 10^3`

C

`2.4 xx 10^(-4)`

D

`1.11`

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The correct Answer is:
To find the cell constant of the solution, we can use the relationship between specific conductance (κ), resistance (R), and the cell constant (L/A). Here’s the step-by-step solution: ### Step-by-Step Solution: 1. **Understand the Relationship**: The cell constant (L/A) can be calculated using the formula: \[ \text{Cell Constant} = \kappa \times R \] where: - \( \kappa \) = specific conductance (ohm\(^{-1}\) cm\(^{-1}\)) - \( R \) = resistance (ohms) 2. **Substitute the Given Values**: From the problem, we know: - \( \kappa = 0.015 \, \text{ohm}^{-1} \text{cm}^{-1} \) - \( R = 60 \, \text{ohms} \) Now, substituting these values into the formula: \[ \text{Cell Constant} = 0.015 \, \text{ohm}^{-1} \text{cm}^{-1} \times 60 \, \text{ohms} \] 3. **Calculate the Cell Constant**: \[ \text{Cell Constant} = 0.015 \times 60 = 0.9 \, \text{cm}^{-1} \] 4. **Conclusion**: The cell constant (L/A) of the solution is \( 0.9 \, \text{cm}^{-1} \). ### Final Answer: The cell constant is **0.9 cm\(^{-1}\)**. ---
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