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Alkyl halide undergoes sequence of react...

Alkyl halide undergoes sequence of reaction to form primary amine. Identify X and Y in the following sequence
`C_2H_5Broverset(X) rarr"Product " overset(Y)rarrC_3H_7NH_2`

A

`X=KCN,Y=H_3O^+`

B

`X=KCN,Y=LiAlH_4`

C

`X=CH_3Cl,Y=AlCl_3//HCl`

D

`X=CH_3NH_2,Y=HNO_2`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we need to identify the reagents X and Y in the reaction sequence that converts bromoethane (C2H5Br) into propanamine (C3H7NH2). ### Step-by-Step Solution: 1. **Identify the Starting Material**: The starting material is bromoethane (C2H5Br). 2. **Determine the Product**: The final product is propanamine (C3H7NH2). This indicates that there is an increase in the carbon chain length from 2 carbons (in bromoethane) to 3 carbons (in propanamine). 3. **Identify Reagent X**: To increase the carbon chain from 2 to 3, we can use a nucleophile that adds a carbon group. A common reagent for this purpose is potassium cyanide (KCN). - **Reaction**: C2H5Br + KCN → C2H5CN (ethanenitrile) This reaction involves an SN2 mechanism where the cyanide ion (CN-) attacks the bromoethane, displacing the bromine atom and forming ethanenitrile. 4. **Identify Reagent Y**: The next step is to convert the nitrile (C2H5CN) into a primary amine (C3H7NH2). A suitable reagent for this reduction is lithium aluminum hydride (LiAlH4). - **Reaction**: C2H5CN + LiAlH4 → C2H5CH2NH2 (propanamine) This reaction reduces the nitrile group to a primary amine. 5. **Conclusion**: Therefore, we have identified: - X = KCN - Y = LiAlH4 ### Final Answer: - X = KCN - Y = LiAlH4
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