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Which statement is not correct about H3B...

Which statement is not correct about `H_3BO_3` ?

A

It is a strong tribasic acid

B

It has a layer structure in which planar `BO_3` units are joined by hydrogen bonds

C

It is prepared by acidifying an aqueous solution of borax

D

It does not act as proton donor but acts as a Lewis acid by accepting hydroxyl ion

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The correct Answer is:
To determine which statement is not correct about \( H_3BO_3 \) (boric acid), we will analyze the properties and characteristics of boric acid step by step. ### Step-by-Step Solution: 1. **Identify the Structure of \( H_3BO_3 \)**: - Boric acid, \( H_3BO_3 \), is also known as ortho-boric acid. Its structure consists of boron (B) surrounded by three hydroxyl groups (OH). The molecular structure can be represented as: \[ \text{B(OH)}_3 \] - The boron atom is at the center, and the three hydroxyl groups are arranged around it. **Hint**: Remember that the structure of boric acid is planar with boron at the center and hydroxyl groups attached. 2. **Determine the Acidic Nature of \( H_3BO_3 \)**: - Boric acid is classified as a weak acid. It does not donate protons (H⁺) like typical acids. Instead, it acts as a Lewis acid by accepting hydroxyl ions (OH⁻) from water, forming tetrahydroxyborate ions. **Hint**: Recall that Lewis acids accept electron pairs, while Brønsted acids donate protons. 3. **Evaluate the Preparation of \( H_3BO_3 \)**: - Boric acid can be prepared by acidifying borax (sodium tetraborate, \( Na_2B_4O_7 \)) with sulfuric acid (\( H_2SO_4 \)). The reaction can be summarized as: \[ Na_2B_4O_7 + H_2SO_4 + H_2O \rightarrow 4 H_3BO_3 + Na_2SO_4 \] **Hint**: Focus on the reaction between borax and sulfuric acid to produce boric acid. 4. **Analyze the Statements**: - **Statement 1**: "It is a strong tribasic acid." - This statement is incorrect because boric acid is a weak monobasic Lewis acid. - **Statement 2**: "It has a layered structure in which planar BO3 units are joined by hydrogen bonds." - This statement is correct. - **Statement 3**: "It is prepared by acidifying an aqueous solution of borax." - This statement is also correct. - **Statement 4**: "It does not act as a proton donor but acts as a Lewis acid by accepting hydroxyl ions." - This statement is correct. **Hint**: Identify which statement contradicts the known properties of boric acid. 5. **Conclusion**: - The statement that is not correct about \( H_3BO_3 \) is the first one: "It is a strong tribasic acid." Therefore, the correct answer is that this statement is false. ### Final Answer: The statement that is not correct about \( H_3BO_3 \) is: **"It is a strong tribasic acid."**
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