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The rms speed of hydrogen molecule at a ...

The rms speed of hydrogen molecule at a certain temperature is v. If the temperature is doubled and hydrogen gas dissociates into atomic hydrogen , the rms speed will become

A

v

B

`v/2`

C

`2v`

D

`sqrt2v`

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The correct Answer is:
To solve the problem, we need to determine the new root mean square (rms) speed of hydrogen atoms after the temperature is doubled and the hydrogen molecules dissociate into atomic hydrogen. ### Step-by-Step Solution: 1. **Understanding the rms Speed Formula**: The rms speed (Vrms) of a gas is given by the formula: \[ V_{\text{rms}} = \sqrt{\frac{3RT}{M}} \] where: - \( R \) is the universal gas constant, - \( T \) is the absolute temperature, - \( M \) is the molar mass of the gas. 2. **Initial Conditions**: - Let the initial rms speed of hydrogen molecules (H₂) at temperature \( T_1 \) be \( V \). - The molar mass of hydrogen molecule (H₂) is \( 2 \times 10^{-3} \, \text{kg/mol} \). 3. **Doubling the Temperature**: When the temperature is doubled, the new temperature \( T_2 \) becomes: \[ T_2 = 2T_1 \] 4. **Dissociation of Hydrogen Molecules**: When hydrogen gas (H₂) dissociates into atomic hydrogen (H), the molar mass of atomic hydrogen is: \[ M_{\text{H}} = 1 \times 10^{-3} \, \text{kg/mol} \] 5. **Calculating New rms Speed**: Now we need to find the new rms speed \( V_2 \) for the atomic hydrogen at the new temperature \( T_2 \): \[ V_2 = \sqrt{\frac{3R(2T_1)}{M_{\text{H}}}} \] Substituting the values: \[ V_2 = \sqrt{\frac{3R(2T_1)}{1 \times 10^{-3}}} \] 6. **Relating to Initial rms Speed**: We know from the initial conditions that: \[ V = \sqrt{\frac{3RT_1}{2 \times 10^{-3}}} \] To find \( V_2 \) in terms of \( V \): \[ V_2 = \sqrt{2} \cdot \sqrt{\frac{3RT_1}{1 \times 10^{-3}}} \] Simplifying further, we can express \( V_2 \) as: \[ V_2 = \sqrt{2} \cdot \sqrt{2} \cdot V = 2V \] 7. **Conclusion**: Therefore, the new rms speed of atomic hydrogen after the temperature is doubled and the molecules dissociate is: \[ V_2 = 2V \] ### Final Answer: The rms speed will become \( 2V \).
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