Home
Class 12
CHEMISTRY
The number of isomers (including stereoi...

The number of isomers (including stereoisomers) of `C_5H_(10)` are

A

10

B

11

C

12

D

13

Text Solution

AI Generated Solution

The correct Answer is:
To determine the number of isomers (including stereoisomers) for the molecular formula \( C_5H_{10} \), we will follow these steps: ### Step 1: Calculate the Degree of Unsaturation The degree of unsaturation (DU) can be calculated using the formula: \[ DU = \frac{(2C + 2 + N - H - X)}{2} \] Where: - \( C \) = number of carbon atoms - \( H \) = number of hydrogen atoms - \( N \) = number of nitrogen atoms (which is 0 in this case) - \( X \) = number of halogen atoms (which is also 0 in this case) Substituting the values for \( C = 5 \) and \( H = 10 \): \[ DU = \frac{(2 \times 5 + 2 + 0 - 10 - 0)}{2} = \frac{(10 + 2 - 10)}{2} = \frac{2}{2} = 1 \] This indicates that there is one degree of unsaturation, which means there could be either a double bond or a ring in the structure. ### Step 2: Identify Possible Structures Given that \( C_5H_{10} \) can have a double bond or a ring, we will explore both options: #### A. Alkenes (Double Bonds) 1. **Straight-chain alkenes**: - **1-Pentene**: CH2=CH-CH2-CH2-CH3 - **2-Pentene**: CH3-CH=CH-CH2-CH3 (can have E/Z isomers) 2. **Branched alkenes**: - **3-Pentene**: CH3-CH2-CH=CH-CH3 (can have E/Z isomers) - **2-Methyl-1-butene**: CH2=C(CH3)-CH2-CH3 - **2-Methyl-2-butene**: CH3-C(CH3)=CH-CH3 (can have E/Z isomers) #### B. Cycloalkanes 1. **Cyclopentane**: A 5-membered ring (C5H10). 2. **Methylcyclobutane**: A 4-membered ring with a methyl group. 3. **1,2-Dimethylcyclopropane**: A 3-membered ring with two methyl groups. ### Step 3: Count All Isomers Now we will count all the unique structures identified: - **Alkenes**: - 1-Pentene - 2-Pentene (E and Z forms) - 3-Pentene (E and Z forms) - 2-Methyl-1-butene - 2-Methyl-2-butene (E and Z forms) This gives us 7 alkenes. - **Cycloalkanes**: - Cyclopentane - Methylcyclobutane - 1,2-Dimethylcyclopropane This gives us 3 cycloalkanes. ### Step 4: Total Isomers Adding the alkenes and cycloalkanes together: - Total = 7 (alkenes) + 3 (cycloalkanes) = 10 isomers. ### Step 5: Include Stereoisomers From the alkenes, we have: - 2-Pentene has 2 stereoisomers (E and Z). - 3-Pentene has 2 stereoisomers (E and Z). - 2-Methyl-2-butene has 2 stereoisomers (E and Z). Adding these gives us additional stereoisomers: - Total stereoisomers = 2 (from 2-Pentene) + 2 (from 3-Pentene) + 2 (from 2-Methyl-2-butene) = 6. ### Final Count Total isomers including stereoisomers: - 10 (from structural isomers) + 6 (from stereoisomers) = 16 isomers. ### Conclusion The total number of isomers (including stereoisomers) of \( C_5H_{10} \) is **16**.
Doubtnut Promotions Banner Mobile Dark
|

Topper's Solved these Questions

  • NTA NEET SET 71

    NTA MOCK TESTS|Exercise CHEMISTRY|45 Videos
  • NTA NEET SET 73

    NTA MOCK TESTS|Exercise CHEMISTRY|45 Videos

Similar Questions

Explore conceptually related problems

The number of isomer (including stereoisomers) of C_(5)H_(12)O which can give positive haloform test is

The number of unbranched isomers (including stereoisomers) of C_(6)H_(12) are

Knowledge Check

  • The total number of acylic isomers (including steroisomers) of C_(4)H_(7)CI is

    A
    `10`
    B
    `9`
    C
    `12`
    D
    `13`
  • The total number of isomers (including steroisomers ) of hydrocarbon with molecular formula C_(4)H_(8) is:

    A
    2
    B
    4
    C
    5
    D
    6
  • The number of isomers including stereoisomers possible for the compound having molecular formula C_4 H_8 is

    A
    one
    B
    two
    C
    three
    D
    four
  • Similar Questions

    Explore conceptually related problems

    The maximum number of isomers (including stereoisomers) that are possible on monochlorination of the following compound, is

    The maximum number of isomers (including stereoisomers ) that are possible on monochlorination of the following compound is :

    The number of possible isomers (including stereoisomers) on monochlorination (Cl_(2)//hv) of the following compound is:

    The toal number of isomers including stereoisomers for 1,3-dimethly cyclohexane is:

    Total number of acyclic isomers including stereoisomers of AlCl_3 find product is