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Identify the correct statements with ref...

Identify the correct statements with reference to the given reaction
`P_(4)+3OH^(-)+3H_(2)OtoPH_(3)+3H_(2)PO_(2)^(-)`

A

Phosphorus is undergoing reduction only

B

Phosphorus is undergoing oxidation only

C

Phosphorus is undergoing oxidation as well as reduction

D

Hydrogen is undergoing neither oxidation nor reduction

Text Solution

Verified by Experts

The correct Answer is:
c,d

Write the O.N. of each element above its symbol, then
`overset(0)(P_(4))+3overset(-2)(O)overset(+1)(H^(-))+3overset(+1)(H_(2))overset(-2)(O)tooverset(-3)(P)overset(+1)(H_(3))+3overset(+1)(H_(2))overset(+1)(P)O_(2)^(-)`
In this reaction, O.N. of P increases from 0 in `P_(4)` to +1 in `H_(2)PO_(2)^(-)` and decreases to -3 in `PH_(3)`, therefore, P undergoes both oxidation as well as reduction. Thus, options (a) and (b) are reduction. Thus, option (d) is correct.
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