Home
Class 11
CHEMISTRY
A solution of H(2)O(2) is titrated again...

A solution of `H_(2)O_(2)` is titrated against a solution of `KMnO_(4)`.
The reaction is :
`2MnO_(4)^(-)+5H_(2)O_(2)+6H^(+) to 2Mn^(2+)+5O_(2)+8H_(2)O`
If it requires 46.9 mL of 0.145 M `KMnO_(4)` to oxidise 20 g of `H_(2)O_(2)`, the mass percentage of `H_(2)O_(2)` in this solution is :

A

2.9

B

29

C

21

D

4.9

Text Solution

Verified by Experts

The correct Answer is:
A

Number of moles of `KMnO_(4)=(MV)/(1000)=(0.145xx46.9)/(1000)`
`=6.8xx10^(-3)`
Number of moles of `H_(2)O_(2)=6.8xx10^(-3)xx2.5=0.017`
Mass of `H_(2)O_(2)=0.017xx34=0.578`
Mass % of `H_(2)O_(2)=(0.578)/(20)xx100=2.9`
Promotional Banner

Topper's Solved these Questions

  • VOLUMETRIC ANALYSIS

    OP TANDON|Exercise Practice Problems|76 Videos
  • VOLUMETRIC ANALYSIS

    OP TANDON|Exercise Objective Question (Level-A)|99 Videos
  • VOLUMETRIC ANALYSIS

    OP TANDON|Exercise Example 27|2 Videos
  • THE COLLOIDAL STATE

    OP TANDON|Exercise Self Assessment|21 Videos

Similar Questions

Explore conceptually related problems

2MnO_(4)^(-)+5H_(2)O_(2)+6H^(-) rarr 2Z+5O_(2)+8H_(2)O . In this reaction Z is

In the redox reaction, 2MnO_(4)^(-)+5C_(2)O_(4)^(2-)+16H^(+) to 2Mn^(2+)+10CO_(2)+8H_(2)O 20mL of 0.1 M KMnO_(4) reacts quantitatively with :

34 g of H_(2)O_(2) is present in H_(2)O mL of solution. This solution is called.

2MnO_(4)^(-) + 5H_(2)O_(2) + 6H^(+) rarr 2Z + 5O_(2) + 8H_(2)O Identify Z in the above reaction.

200 ml of 0.01 M KMnO_(4) oxidise 20 ml of H_(2)O_(2) sample in acidic medium. The volume strength of H_(2)O_(2) is

OP TANDON-VOLUMETRIC ANALYSIS-Illustrations
  1. A metal M of equivalent mass E forms an oxide of molecular formula M(x...

    Text Solution

    |

  2. In the reaction, FeS(2)+KMnO(4)+H^(+) to Fe^(3+)+SO(2)+Mn^(2+)+H(2)O...

    Text Solution

    |

  3. The equivalent mass of H(3)BO(3) in its reaction with NaOH to form Na(...

    Text Solution

    |

  4. For the reaction, N(2)(g)+3H(2)(g)to 2NH(3)(g), if molecular masses of...

    Text Solution

    |

  5. X gm of metal gave Y gm of its oxide, so equivalent mass of metal is :

    Text Solution

    |

  6. KMnO(4) (m.w.=158) oxidises oxalic acid in acid medium to CO(2) and wa...

    Text Solution

    |

  7. The formula mass of Mohr's salt is 392. The iron present in it is oxid...

    Text Solution

    |

  8. In a redox reaction, dichromate ion (Cr(2)O(7)^(2-)) is reduced to Cr^...

    Text Solution

    |

  9. How many grams of NaHCO(3) are required to neutralise 1 mL of 0.0902 N...

    Text Solution

    |

  10. 0.7 g " of " Na(2)CO(3).xH(2)O were dissolved in water and the volume ...

    Text Solution

    |

  11. Calculate the equivalent mass of Na(2)CO(3) when it is titrated agains...

    Text Solution

    |

  12. 1 mol H(2)SO(4) will exactly neutralise :

    Text Solution

    |

  13. Which of the following gives equivalent mass of Na(2)CO(3) when titrat...

    Text Solution

    |

  14. How many moles of MnO(4)^(-) ions will react with 1 mole of ferrous ox...

    Text Solution

    |

  15. The molecular mass of K(2)Cr(2)O(7) is 294 amu. It acts as oxidising a...

    Text Solution

    |

  16. In acid medium, both KMnO(4) " and " K(2)Cr(2)O(7) act as oxidising ag...

    Text Solution

    |

  17. KMnO(4) reacts with oxalic acid according to the equation, 2MnO(4)^(...

    Text Solution

    |

  18. A solution of H(2)O(2) is titrated against a solution of KMnO(4). Th...

    Text Solution

    |

  19. In an oxidation-reduction, MnO(4)^(-) ion is converted to Mn^(2+), wha...

    Text Solution

    |

  20. The strenth of 10 volume of H(2)O(2) solution is :

    Text Solution

    |