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The ammonia evolved from 2 g of a compou...

The ammonia evolved from 2 g of a compound in Kjeldahl's estimation of nitrogen neutralizes 10 mL of 2 M `H_(2)SO_(4)` solution. The weight percentage of nitrogen in the compound is :

A

28

B

14

C

56

D

7

Text Solution

AI Generated Solution

The correct Answer is:
To find the weight percentage of nitrogen in the compound, we will follow these steps: ### Step 1: Calculate the moles of `H2SO4` used Given: - Volume of `H2SO4` = 10 mL = 10 × 10^(-3) L - Molarity of `H2SO4` = 2 M Using the formula: \[ \text{Moles of } H2SO4 = \text{Molarity} \times \text{Volume (in L)} \] \[ \text{Moles of } H2SO4 = 2 \, \text{mol/L} \times 10 \times 10^{-3} \, \text{L} = 0.02 \, \text{mol} \] ### Step 2: Determine the moles of `NH3` neutralized The reaction between `NH3` and `H2SO4` is: \[ 2 \, NH3 + H2SO4 \rightarrow (NH4)2SO4 \] From the stoichiometry of the reaction, 1 mole of `H2SO4` reacts with 2 moles of `NH3`. Therefore, the moles of `NH3` can be calculated as: \[ \text{Moles of } NH3 = 2 \times \text{Moles of } H2SO4 = 2 \times 0.02 \, \text{mol} = 0.04 \, \text{mol} \] ### Step 3: Calculate the mass of `NH3` The molar mass of `NH3` (ammonia) is approximately 17 g/mol. Thus, the mass of `NH3` can be calculated as: \[ \text{Mass of } NH3 = \text{Moles} \times \text{Molar Mass} = 0.04 \, \text{mol} \times 17 \, \text{g/mol} = 0.68 \, \text{g} \] ### Step 4: Calculate the weight percentage of nitrogen in the compound The compound weighs 2 g, and the nitrogen in `NH3` contributes to the total nitrogen in the compound. The mass of nitrogen in `NH3` can be calculated as: \[ \text{Mass of Nitrogen} = \text{Moles of } NH3 \times \text{Molar Mass of Nitrogen} = 0.04 \, \text{mol} \times 14 \, \text{g/mol} = 0.56 \, \text{g} \] Now, we can calculate the weight percentage of nitrogen in the compound: \[ \text{Weight percentage of Nitrogen} = \left( \frac{\text{Mass of Nitrogen}}{\text{Mass of Compound}} \right) \times 100 = \left( \frac{0.56 \, \text{g}}{2 \, \text{g}} \right) \times 100 = 28\% \] ### Final Answer: The weight percentage of nitrogen in the compound is **28%**. ---

To find the weight percentage of nitrogen in the compound, we will follow these steps: ### Step 1: Calculate the moles of `H2SO4` used Given: - Volume of `H2SO4` = 10 mL = 10 × 10^(-3) L - Molarity of `H2SO4` = 2 M Using the formula: ...
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