Home
Class 12
CHEMISTRY
The products formed when an aqueous solu...

The products formed when an aqueous solution of `NaBr` is electrolysed in a cell having inert electrodes are `:`

A

Na and `Br_(2)`

B

Na and `O_(2)`

C

`H_(2),Br_(2)` and NaOH

D

`H_(2)` and `O_(2)`

Text Solution

Verified by Experts

The correct Answer is:
C

`NaBr(aq)hArrNa^(+)(aq)+Br^(-)(aq)`
`Na^(+)+e^(-)rarrNa`
`2H_(2)O+ 2e^(-)rarrH_(2)=2OH^(-)`
As R.P. of 2nd reactions is more `H_(2)` is produced at cathode
`2Br^(-)rarrBr_(2)+2e^(-)`
`2H_(2)OrarrO_(2)+4 H^(+)+4e^(-)`
As O.P. of 1st reaction is more, `Br_(2)` is produced at anode `Na^(+)` from ionisation of NaBr and `OH^(-)` ions produced due to reduction of water at cathode combine to give NaOH.
Promotional Banner

Topper's Solved these Questions

  • ELECTROCHEMISTRY

    DINESH PUBLICATION|Exercise MATCH-MATRIX|7 Videos
  • ELECTROCHEMISTRY

    DINESH PUBLICATION|Exercise ASSERTION AND REASON|20 Videos
  • ELECTROCHEMISTRY

    DINESH PUBLICATION|Exercise REVISION QUESTIONS FROM COMPETITIVE EXAMS|198 Videos
  • D-AND -F BLOCK ELEMENTS

    DINESH PUBLICATION|Exercise BRAIN STORMING MULTIPLE CHOICE QUESTIONS (MCQS)|13 Videos
  • ETHERS

    DINESH PUBLICATION|Exercise (MCQs)|8 Videos

Similar Questions

Explore conceptually related problems

Which is evolved at cathode when an aqueous solution of NaCl is electrolysed ?

When aqueous solution of KCl is electrolysed, resultant solution has

When an aqueous concentrated solution of lithium chloride is electrolysed using inert electrodes:

The reaction taking place at the anode when a dilute aqueous solution of CuSO_(4) is electrolysed using inert Pt electrodes.

If aqueous solutions of AgNO_3 is electrolysed using inert electrode the gas evolved at anode is .

when an aqueous solution of H_2SO_4 is electrolysed the product at anodes is :

When an aqueous of potassium ethanote is electrolysed ?

DINESH PUBLICATION-ELECTROCHEMISTRY-SELECTED STRAIGHT OBJECTIVE
  1. If E(Fe^(2+))^(@)//Fe = -0.441 V and E(Fe^(3+))^(@)//Fe^(2+) = 0.771...

    Text Solution

    |

  2. The charge required for the reduction of 1 mol of MnO(4)^(-) to MnO(2)...

    Text Solution

    |

  3. The products formed when an aqueous solution of NaBr is electrolysed i...

    Text Solution

    |

  4. Calculate the equilibrium constant for the reaction Cu(s)+2Ag^(+)(aq)r...

    Text Solution

    |

  5. The efficiency of a fuel cell is given by:

    Text Solution

    |

  6. The equivalent conductances of two strong electrolytes at infinite di...

    Text Solution

    |

  7. The cell , Zn | Zn^(2+) (1M) || Cu^(2+) (1M) Cu (E("cell")^@ = 1. 10 V...

    Text Solution

    |

  8. Electrolysis of dilute aqueous NaCl solution was carried out by passin...

    Text Solution

    |

  9. On the basis of the following E^(@) values, the stongest oxidizing age...

    Text Solution

    |

  10. The seqeunce of ionic mobility in the aqueous solution is

    Text Solution

    |

  11. Standard free energies of formation (I kJ //mol ) at 298 K are -237 ....

    Text Solution

    |

  12. Given E(Cr^(3+)//Cr)^(@)=-0.72V, and E(Fe^(2+)//Fe)^(@)=-0.42V The...

    Text Solution

    |

  13. Given,{:(E(Fe^(3+) //Fe)^o + 3e Cr E^o =- 0.036 V),(E(Fe^(3+) //Fe)^o...

    Text Solution

    |

  14. The equivalent conductance of M//32 solution of a weak monobasic acid ...

    Text Solution

    |

  15. Consider the following relations for (i) EMF of the cell =(Oxidati...

    Text Solution

    |

  16. The Gibbs energy for the decomposition of Al(2)O(3) at 500^(@)C is as ...

    Text Solution

    |

  17. An increase in equivalent conductance of a strong electrolyte with dil...

    Text Solution

    |

  18. For the reduction of silver ions with copper metal, the standard cell ...

    Text Solution

    |

  19. Which of the following expressions correctly repesents the equivalent ...

    Text Solution

    |

  20. The reduction potential of hydrogen half cell will be negative if :

    Text Solution

    |