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For the gaseous reaction involving the c...

For the gaseous reaction involving the complete combustion of iso-butane

A

`DeltaH=DeltaE`

B

`DeltaHgtDeltaE`

C

`DeltaH=DeltaE=0`

D

`DeltaHltDeltaE`

Text Solution

Verified by Experts

The correct Answer is:
B

The gas phase combustion of isobutane `(C_(4)H_(10))` represented as
`C_(4)H_(10)(g)+13//2O_(2)(g)to4CO_(2)(g)+5H_(2)O(g)`
`Deltan_(g)=9-((13)/(2)+1)=9-(15)/(2)=+(3)/(2)`
Since `Deltan_(g)=+ve`
Thus `DeltaH gt E`
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