Home
Class 12
CHEMISTRY
For hypothetical reversible reaction 1...

For hypothetical reversible reaction
`1//2A_(2)(g) +3//2B_(2)(g) rarr AB_(3)(g), DeltaH =- 20 kJ `if standard entropies of `A_(2),B_(2)`, and `AB_(3)` are `60,40` and `50JK^(-1) mol^(-1)` respectively. The above reaction will be equilibrium at

A

`400 K`

B

`500K`

C

`250K`

D

`200K`

Text Solution

Verified by Experts

The correct Answer is:
B

At equilibrium, `DeltaH=T DeltaS`
`T=(DeltaH)/(DeltaS)=(-20xx10^(3)J)/((50-3//2xx40-1//2xx60))`
`:. T= 500 K`
Promotional Banner

Topper's Solved these Questions

  • CHEMICAL KINETICS

    DINESH PUBLICATION|Exercise Additional Numerical Problems For Practice|16 Videos
  • CHEMISTRY IN EVERY DAY LIFE

    DINESH PUBLICATION|Exercise Unit test-9|50 Videos

Similar Questions

Explore conceptually related problems

For reversible reaction : X_((g))+3Y_((g))hArr 2Z_((g)), DeltaH=-"40 kJ" Standard entropies of X, Y and Z are 60, 40and "50 J K"^(-1)",ol"^(-1) respectively. The temperature at which the above reaction is in equilibrium is

For the reaction (1)/(2) N_(2)(g) + (3)/(2) H_(2)(g) rarr NH_(3)(g), DeltaH =-30 KJ to be at equilibrium at 477^(@) C. If standard entropy of N_(2)(g) and NH_(3)(g) are 60 and 50 "J" "mole"^(-1)K^(-1) respectively then calculate the standard entropy of H_(2)(g) in "J mole"^(-1) K^(-1).

For a hypothetical reaction of kind. AB_(2)(g)+1/2 B_(2)(g) hArr AB_(3)(g), DeltaH=-x kJ More AB_(3) could be produceed at equilibrium by

In a reaction A_(2)(g)+4B_(2)(g) hArr 2AB_(4)(g), DeltaH lt 0 . The formation of AB_(4) is not favoured by

The enthalpy and entropy change for the reaction, Br_(2)(l)+Cl_(2)(g)rarr2BrCl(g) are 30KJmol^(-1) and 105JK^(-1)mol^(-1) respectively. The temperation at which the raction will be in equilibrium is:

DINESH PUBLICATION-CHEMICAL THERMODYNAMICS AND CHEMICAL ENERGETICS -Exercise
  1. One moles of anhydrous AB dissolves in water and liberates 21.0 J mol^...

    Text Solution

    |

  2. The standard entropies of N(2)(g),H(2)(g) and NH(3)(g) are 191.5, 130....

    Text Solution

    |

  3. For hypothetical reversible reaction 1//2A(2)(g) +3//2B(2)(g) rarr A...

    Text Solution

    |

  4. If DeltaH(f)^(@) of Icl(g), Cl(g) and I(g) is 17.57, 121.34 and 106.96...

    Text Solution

    |

  5. If the enthalpy of combustion of C(graphite) is -393.3kJ mol^(-1), the...

    Text Solution

    |

  6. An ideal gas expands from 10^(-3) m^(3) to 10^(-2) m^(3) at 300 K agai...

    Text Solution

    |

  7. The equilibrium constant for certain reaction is 100. If the value R i...

    Text Solution

    |

  8. Bond dissociation energy of O(2)(g) is x k J mol^(-1). This means that

    Text Solution

    |

  9. H(2)O(l)toH(2)O(g) , DeltaH=+43.7 kJ H(2)O(s)toH(2)O(l) , DeltaH=+6....

    Text Solution

    |

  10. Given that CH(4)(g) +360 kJ rarr C(g) +4H(g) C(2)H(6)(g) +620 kJ r...

    Text Solution

    |

  11. For a reaction Br(2)(l)+Cl(2)(g)to2BrCl at 300K the value of DeltaH=...

    Text Solution

    |

  12. At what temperature, DeltaG of a reaction is equal to -5.2 kJ mol^(-1)...

    Text Solution

    |

  13. For a reaction A(g)+3B(g)to2C(g) , DeltaH^(@)=-24kJ The value of D...

    Text Solution

    |

  14. Consider the following reaction at equilibrium 2Fe^(2+)(aq)+Cu^(2+)to2...

    Text Solution

    |

  15. A gas absorbs 400J of heat and expands by 2 xx 10^(-3) m^(3) against a...

    Text Solution

    |

  16. The enthalpy of formation of ammonia is -46.0 kJ mol^(-1). The enthalp...

    Text Solution

    |

  17. Which one of the following relations is incorrect ?

    Text Solution

    |

  18. The work done by the system in a cyclic process involving one mole of ...

    Text Solution

    |

  19. The work done by the system in the conversion of 1 mol of water at 100...

    Text Solution

    |

  20. If DeltaH(f)(X), DeltaH(f)(Y), DeltaH(f)(R ) and DeltaH(f)(S) denote t...

    Text Solution

    |