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If S+O(2)toSO(2),DeltaH=-298.2 " kJ" " m...

If `S+O_(2)toSO_(2),DeltaH=-298.2 " kJ" " mole"^(-1)`
`SO_(2)+(1)/(2)O_(2)toSO_(3)DeltaH=-98.7 " kJ" " mole"^(-1)`
`SO_(3)+H_(2)OtoH_(2)SO_(4),DeltaH=-130.2 " kJ" " mole"^(-1)`
`H_(2)+(1)/(2)O_(2)toH_(2)SO_(4),DeltaH=-287.3 " kJ" " mole"^(-1)`
the enthlapy of formation of `H_(2)SO_(4)` at 298 K will be

A

`-814.4 kJ`

B

`-650.3 kJ`

C

`-320.5 kJ`

D

`-433.5 kJ`

Text Solution

Verified by Experts

The correct Answer is:
A

`H_(2)+S+2O_(2)toH_(2)SO_(4)`…..`DeltaH_(f)`
To get this expression add `(i)`, `(ii)`, `(iii)` and `(iv)`
`DeltaH_(f)=-298.2-98.7-130.22-287.3`
`=-814.4 kJ`
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Given: (i) S+O_2 to SO_2, Delta H=-298.2 kJ (ii) SO_2 + 1/2 O_2 to SO_3, Delta H=-98.7 kJ (iii) SO_3 + H_2 O to H_2 SO_4, Delta H=-130.2 kJ (iv) H_2 + 1/2 O_2 to H_2 O, Delta H=-287.3 kJ , Then the enthalpy of formation of H_2 SO_4 at 298 K will be _________ .

If {:(SO_(2)+1/2O_(2) rarr SO_(3),DeltaH = -98.7 kJ),(SO_(3)+H_2O rarr H_(2)SO_(4),DeltaH = -130.2 kJ),(H_(2)+1/2O_(2) rarr H_2O , Delta H = -287.3 kJ),(S + H_2 + 2O_(2) rarr H_2SO_4, DeltaH = -814.4 kJ):} Then enthaply of SO_(2) at 298 K is:

Given that (1)/(2)S_(8)(s)+6O_(2)(g)to4SO_(3)(g) , DeltaH^(@)=-1590 kJ The standard enthalpy of formation of SO_(3) is

{:(C+O_(2)(g)rarrCO_(2)" ......(i),",DeltaH=-"393 k J mol"^(-1)),(H_(2)+1//2O_(2)rarr H_(2)O", .....(ii)",DeltaH=-"287.3 k J mole"^(-1)),(2CO_(2)+2H_(2)O rarr C_(2)H_(5)OH+2O_(2)" .....(iii)",DeltaH="1366.8 kJ mol"^(-1)):} Find the standard enthalpy of formation of C_(2)H_(5)OH(l)

If, S+O_2 rarr SO_2, Delta H =-298.2 kj SO_2 + 1/2 O_2 rarr SO_3, Delta H=-98.7 kJ SO_3 + H_2 O rarrr H_2SO_4 , Delta H =-130.2 kJ H_2 + 1/2 O_2 rarr H_2 O, Delta H =-227.3 kJ Find Delta H for formation of H_2SO_4 at 298 K.

DINESH PUBLICATION-CHEMICAL THERMODYNAMICS AND CHEMICAL ENERGETICS -Exercise
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  2. The enthalpy change at 298 K of the reaction H(2)O(2)(l)toH(2)O(l)+1...

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  3. If S+O(2)toSO(2),DeltaH=-298.2 " kJ" " mole"^(-1) SO(2)+(1)/(2)O(2)t...

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  4. The entropy change for the fusion of 1 mol of a solid which melts at 2...

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  5. The heat change for the following reaction at 298 K and constant press...

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  6. Which of the following equations express DeltaH as heat of combustion ...

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  7. The enthalpy of formation of ammonia is -46.0 KJ mol^(-1) . The entha...

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  8. The heat evolved in combustion of benzene is given by the following eq...

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  9. DeltaG for a reaction at 300 K is -16 kcal and DeltaH is -10 kcal. The...

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  10. Enthalpy of neutralisation of NH(4)OH and HCl is numerically

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  11. The following are the heats of reactions - (i) Delta H(f)^(@) of H(2...

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  12. The heat of combustion of CH(4(g)), C((g)) and H(2(g)) at 25^(@)C are ...

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  13. One mole of ice is converted into water at 273 K. The entropies of H(2...

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  14. The equilibrium constant for a reaction is 10. What will be the value ...

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  15. One mole of an ideal gas expanded freely and isothermally at 300 K fro...

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  16. For the reaction C(6)H(12)(l)+9O(2)(g)to6H(2)O(l)+6CO(2)(g) , DeltaH...

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  17. Given that the data for neutralization of weak acid (HA) and strong ac...

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  18. A system absorbs 10 kJ of heat at constant volume and its temperature ...

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  19. How many kcal of heat is evolved by the complete neutralisation of one...

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