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A system absorbs 10 kJ of heat at consta...

A system absorbs `10 kJ` of heat at constant volume and its temperature rises from `27^(@)C` to `37^(@)C`. The `DeltaE` of reaction is

A

`100 kJ`

B

`10 kJ`

C

`0`

D

`1 kJ`

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The correct Answer is:
To solve the problem, we need to determine the change in internal energy (ΔE) of the system when it absorbs heat at constant volume. Here are the steps to find the solution: ### Step 1: Understand the relationship between heat absorbed and internal energy At constant volume, the heat absorbed by the system (Q) is equal to the change in internal energy (ΔE). This is a fundamental principle in thermodynamics. ### Step 2: Identify the given values From the problem, we know: - Heat absorbed (Q) = 10 kJ - The temperature change is from 27°C to 37°C, but this information is not needed to calculate ΔE at constant volume. ### Step 3: Apply the relationship Since we are at constant volume, we can directly state: \[ \Delta E = Q \] ### Step 4: Substitute the known value Now, substituting the value of Q into the equation: \[ \Delta E = 10 \, \text{kJ} \] ### Step 5: Final answer Thus, the change in internal energy (ΔE) of the reaction is: \[ \Delta E = 10 \, \text{kJ} \] ---

To solve the problem, we need to determine the change in internal energy (ΔE) of the system when it absorbs heat at constant volume. Here are the steps to find the solution: ### Step 1: Understand the relationship between heat absorbed and internal energy At constant volume, the heat absorbed by the system (Q) is equal to the change in internal energy (ΔE). This is a fundamental principle in thermodynamics. ### Step 2: Identify the given values From the problem, we know: - Heat absorbed (Q) = 10 kJ ...
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DINESH PUBLICATION-CHEMICAL THERMODYNAMICS AND CHEMICAL ENERGETICS -Exercise
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  3. A system absorbs 10 kJ of heat at constant volume and its temperature ...

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  4. How many kcal of heat is evolved by the complete neutralisation of one...

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  5. Given Delta(i)H^(Theta)(HCN) = 45.2 kJ mol^(-1) and Delta(i)H^(Theta)(...

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  6. Calculate the work done when 1.0 mol of water at 373K vaporises agains...

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  7. The maximum efficiency of heat engine operating between 100 ^(@) and 2...

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  8. A gas absorbs 250 J of heat and expands from 1 litre to 10 litres agai...

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  9. Which of the following value of DeltaH(f)^(@) represent that the produ...

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  10. The enthalpies of formation of N(2)O and NO are respectively 82 and 90...

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  11. The value of DeltaH(O-H) is 109 kcal mol^(-1). Then formation of one m...

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  12. The heat of combustion of yellow phoshphorus and red phosphorus are -9...

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  13. For a system in equilibrium, DeltaG=0, under conditions of constant

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  14. In the reversible reaction of the type A+B hArr AB, in general.

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  15. Given C(s)+O(2)(g)toCO(2)(g), DeltaH=-395 kJ S(s)+O(2)(g)toSO(2)(g...

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  16. In an electrochemical cell, if E^(@) is the e.m.f. of the cell involvi...

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  17. If the enthalpy of vaporisation of water is 186.5 J mol^(-1), then ent...

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  18. The DeltaH value for reaction C+(1)/(2)O(2)toCO and CO+(1)/(2)O(2)to...

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  19. Given : C("diamond")+O(2)rarrCO(2),DeltaH=-395 kJ C("graphite"...

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  20. The law of Lavoisier and Laplace illustrates

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