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{:(Given :,C+2StoCS(2),DeltaH=117 kJ),(,...

`{:(Given :,C+2StoCS_(2),DeltaH=117 kJ),(,C+O_(2)toCO_(2),DeltaH=-393 kJ),(,S+O_(2)toSO_(2), DeltaH=-297 kJ):}`
The heat is combustion of `CS_(2)` to form `CO_(2)` and `SO_(2)` is

A

`-1104 kJ mol^(-1)`

B

`+1104 kJ mol^(-1)`

C

`+807 kJ mol^(-1)`

D

`-807 kJ mol^(-1)`

Text Solution

Verified by Experts

The correct Answer is:
A

`CS_(2)+O_(2)toCO_(2)+2SO_(2)`
`DeltaH=[2 DeltaH_(f)(SO_(2))+DeltaH_(f)(CO_(2))]-[DeltaH_(f)(O_(2))+DeltaH_(f)(CS_(2))]`
`=[2xx(-297)+(-393)]-[0+(117)]`
`=-1104 kJ mol^(-1)`
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DINESH PUBLICATION-CHEMICAL THERMODYNAMICS AND CHEMICAL ENERGETICS -Exercise
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  2. The free energy change DeltaG = 0, when

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  3. {:(Given :,C+2StoCS(2),DeltaH=117 kJ),(,C+O(2)toCO(2),DeltaH=-393 kJ),...

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  4. The enthalpies of combustion of carbon and carbon monoxide are -390 kJ...

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  5. The combustion reaction occuring in an automobile is 2C(8)H(18)+25O(2)...

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  6. Latent heat of vaporisation of a liquid at 500K and 1 atm pressure is ...

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  7. The table given below lists the bond dissociation energy (E("diss")) f...

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  8. The enthalpy of formation for C(2)H(4)(g), CO(2)(g) and H(2)O(l) at 25...

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  9. For a reaction to occur spontaneously

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  10. For a process to be spontaneous

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  11. A particular reaction has a negative value for the free energy change...

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  12. The calorific value of fat is

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  13. The heat of formation of the compound in the following reaction is H...

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  14. When water is added to quick lime, the reaction is

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  15. Which relation is correct ?

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  16. Variation of heat of reaction with temperature is known as

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  17. Enthalpy of reaction DeltaH is expressed as

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  18. Heat capacity is

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  19. Given that C+O(2)rarrCO(2),DeltaH^(@)=-xKJ and 2CO+O(2)rarr2CO(2),Delt...

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  20. The enthalpy change of a reaction does not depend on

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