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An endotthermic reaction is non-spontane...

An endotthermic reaction is non-spontaneous at freezing point of water and becomes feasible at its boiling point, then:

A

`DeltaH` is `-ve`, `DeltaS` is `+ve`

B

`DeltaH` and `DeltaS` both are `+ve`

C

`DeltaH` and `DeltaS` both are `-ve`

D

`DeltaH` is `+ve`, `DeltaS` is `-ve`

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The correct Answer is:
B

For an endothermic reaction, `DeltaH=+ve`. Thus `DeltaH` is not favourable. As the reaction becomes spontaneous at higher temperature `DeltaS` has to be `+ve` (i.e., favourable).
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Free enegry , G = H - TS , is state function that indicates whther a reaction is spontaneous or non-spontaneous. If you think of TS as the part of the system's enegry that is disordered already, then (H -TS) is the part of the system's energy that is still ordered and therefore free to cause spontaneous change by becoming disordered. Also, DeltaG = DeltaH - T DeltaS From the second law of thermodynamics, a reaction is spontaneous if Delta_("total")S is positive, non-spontaneous if Delta_("total")S is negative, and at equilibrium if Delta_('total")S is zero. Since, -T DeltaS = DeltaG and since DeltaG and DeltaS have opposite sings, we can restate the thermodynamic criterion for the spontaneity of a reaction carried out a constant temperature and pressure. IF DeltaG lt 0 , the reaction is spontaneous. If DeltaG gt 0 , the reaction is non-spontaneous. If DeltaG = 0 , the reaction is at equilibrium. Read the above paragraph carefully and answer the following questions based on the above comprehension. If an endothermic reaction is non-spontaneous at freezing point of water and becomes feasible at its boiling point, then

If an endothermic reaction is non - spontaneous at freezing of water and becomes feasible at its boiling point, then

A reaction is non-spontaneous when:

Boiling point of water

The following reaction is non-spontaneous

DINESH PUBLICATION-CHEMICAL THERMODYNAMICS AND CHEMICAL ENERGETICS -Exercise
  1. The heat required to raise the temperature of a body by 1 K is called

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  2. A heat engine absorbs heat Q(1) at temperature T(1) and Q(2) at temper...

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  3. An endotthermic reaction is non-spontaneous at freezing point of water...

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  4. Compounds with high heat of formation are less stable because

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  5. Which of the following statements is true ?

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  6. The intensive property among these quantities is

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  7. An adiabatic expansion of an Ideal gas always has

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  8. The favourable conditions for a spontaneous reaction are

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  9. In a closed insulated container, a liquid is stirred with a paddle to ...

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  10. C("diamond")toC("Graphite"), DeltaH=-ve. Then shows that

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  12. Mechanical work is specially important in systems that contain

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  13. The law formulated by Nernst is

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  14. Heat exchanged in a chemical reaction at constant temperature and pres...

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  15. Heat of combustion DeltaH^(@) for C(s),H(2)(g) and CH(4)(g) are 94, -6...

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  16. The enthalpy of formation of ammonia is - 46.2 mol^(-1). The enthalpy ...

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  17. The molar heat capacity of water at constant pressure, C(P) , is 75 JK...

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  18. What is the entropy change (in JK^(-1)mol^(-1)) when one mole of ice i...

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  19. For which one of the following equation is DeltaH(reaction)^(@) equal ...

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  20. If a 298K the bond energies of C-H,C-C,C=C and H-H bonds are respectiv...

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