Home
Class 12
CHEMISTRY
A reaction occurs spontaneously if:...

A reaction occurs spontaneously if:

A

`TDeltaS lt DeltaH` and both `DeltaH` and `DeltaS` are `+ve`

B

`TDeltaS gt DeltaH` and both `DeltaH` and `DeltaS` are `+ve`

C

`TDeltaS = DeltaH` and both `DeltaH` and `DeltaS` are `+ve`

D

`TDeltaS lt DeltaH` and `DeltaH` is `+ve` and `DeltaS` is `-ve`

Text Solution

Verified by Experts

The correct Answer is:
B

`DeltaG=DeltaH-TDeltaS`
When both `DeltaH` and `DeltaS` are `+ve`, for reaction to be spontaneous `(DeltaG lt0)`, `TDeltaS gt DeltaH` (When `DeltaH` is `+ve` and `DeltaS` is `-ve`, the reaction in never spontaneous)
Promotional Banner

Topper's Solved these Questions

  • CHEMICAL KINETICS

    DINESH PUBLICATION|Exercise Additional Numerical Problems For Practice|16 Videos
  • CHEMISTRY IN EVERY DAY LIFE

    DINESH PUBLICATION|Exercise Unit test-9|50 Videos

Similar Questions

Explore conceptually related problems

A reaction occurs spontaneously in forward direction if

If an eddothermic reaction occurs spontaneously at constant temperature and pressure, then which of the following is true?

If an endothermic reaction occurs spontaneously at constant T and P , then which of the following is true

The enthalpy change for a given reaction at 298 K is -x cal mol^(-1) . If the reaction occurs spontaneously at 298 K , the entropy change at that temperature

For a reaction both DeltaH and DeltaS are positive.Under what conditions does the reaction occur spontaneously?

For a reaction both DeltaH and DeltaS are positive.Under what conditions does the reaction occur spontaneously?

Relate free energy with equillibrium constant. For a reaction both DeltaH and DeltaS are positive.Under what conditions does the reaction occur spontaneously?

DINESH PUBLICATION-CHEMICAL THERMODYNAMICS AND CHEMICAL ENERGETICS -Exercise
  1. DeltaH and DeltaS for a reaction are +30.558 kJ mol^(-1) and 0.66 kJ m...

    Text Solution

    |

  2. What would be the heat released when an aqueous solution containing 0....

    Text Solution

    |

  3. A reaction occurs spontaneously if:

    Text Solution

    |

  4. The absolute enthalpy of neutralization of the reaction, MgO(s)+2HCl...

    Text Solution

    |

  5. For a spontaneous reaction, DeltaG, equilibrium constant (K) and E(cel...

    Text Solution

    |

  6. Consider the reaction: N(2) + 3H(2) hArr 2NH(3) carried out at constan...

    Text Solution

    |

  7. If the bond dissociation energies of XY,X(2) and Y(2)( all diatomic mo...

    Text Solution

    |

  8. Which of the following pairs of a chemical reaction is certaion to res...

    Text Solution

    |

  9. Which of the following is nor correct ?

    Text Solution

    |

  10. If the heat of neutralization for a strong acid - base reaction is -5...

    Text Solution

    |

  11. The heats fo neutralization of HCl with NH(4) OH and NaOH with CH(3) C...

    Text Solution

    |

  12. Five mole of a gas put through a series of change as shown below graph...

    Text Solution

    |

  13. A process is taking place at constant temperature and pressure. Then

    Text Solution

    |

  14. One mole of a perfect gas expands isothermally to ten times its origin...

    Text Solution

    |

  15. AtoB , DeltaH=4 kcal mol^(-1), DeltaS=10 cal mol^(-1)K^(-1). Reaction ...

    Text Solution

    |

  16. The sublimation energy of I(2) (solid) is 57.3 KJ/mole and enthalpy o...

    Text Solution

    |

  17. For the reaction: 2H(2)(g) +O(2)(g) rarr 2H(2)O(g), DeltaH =- 571 kJ...

    Text Solution

    |

  18. The standard molar heats of formation of ethane, carbon dioxide, and l...

    Text Solution

    |

  19. 0.06 mole of KNO(3) is added to 100cm^(3) of water at 298 K. The entha...

    Text Solution

    |

  20. Which of the following equations does not correctly represent the firs...

    Text Solution

    |