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For a spontaneous reaction, DeltaG, equi...

For a spontaneous reaction, `DeltaG,` equilibrium constant (K) and `E_(cell)^(@)` will be respectively:

A

`-ve`, `gt 1`, `+ve`

B

`+ve`, `gt 1`, `-ve`

C

`-ve`, `lt 1`, `-ve`

D

`-ve`, `gt 1`, `-ve`

Text Solution

Verified by Experts

The correct Answer is:
A

For a spontaneous reaction `DeltaG` is `-ve`
`DeltaG=-RT ln K`
or `ln K` is `+ve implies K gt1`
Now `DeltaG=-nFE_("cell")`
As `DeltaG` is `-ve` for a spontaneous reaction. `E_("cell")` for such a reaction is `+ve`.
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DINESH PUBLICATION-CHEMICAL THERMODYNAMICS AND CHEMICAL ENERGETICS -Exercise
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