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A spontaneous reaction is impossible if...

A spontaneous reaction is impossible if

A

both `DeltaH` and `DeltaS` are negative

B

both `DeltaH` and `DeltaS` are positive

C

`DeltaH` is negative and `DeltaS` is positive

D

`DeltaH` is positive and `DeltaS` is negative

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The correct Answer is:
D

For a reaction to be non-spontaneous, `DeltaG gt 0`. It can happen when both `DeltaH` and `DeltaS` are unfavourable i.e., when `DeltaH` is `+ve` and `DeltaS` is `-ve`
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Statement-1 : All the exothermic reactions are spontaneous. And Statement-2 : For a spontaneous reaction, Delta G must be negative.

DINESH PUBLICATION-CHEMICAL THERMODYNAMICS AND CHEMICAL ENERGETICS -Exercise
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  6. In which of the following reactions, the enthalpy is the least ?

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  7. According to the first law of thermodynamics which of the following qu...

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  8. A 1.0g sample of substance A at 100^(@)C is added to 100 mL of H(2)O ...

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  9. The amount of heat evolved when 500 cm^(3) 0.1 M HCl is mixed with 200...

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  10. Based on first law of thermodynamics, which one of the following is co...

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  11. The value of enthalpy change (DeltaH) for the reaction C(2)H(5)OH (l...

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  12. Which of the following is correct option for the free expansion of an ...

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  13. The entropy change involved in the isothermal reversible expansion of ...

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  14. Enthalpy change for the reaction 2H(2)(g)rarr4H(g) is -869.6kJ Th...

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  15. Consider the reaction, 4NO(2)(g)+O(2)(g)rarr2N(2)O(5)(g),Delta(r )H=...

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  16. In view of the signs of Delta(r)G^(0) for the following reactions Pb...

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  17. Consider the following processes :- {:(,DeltaH(kJ//mol)),((1)/(2)A r...

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  18. At the sublimation temperature, for the process CO(2)(S)toCO(2)(g)

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  19. Which of the following sets of conditions would result in a reaction t...

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