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Which of the following reactions will de...

Which of the following reactions will define `DeltaH_(f)^(@)` ?

A

`C("diamond")+O_(2)(g)toCO_(2)(g)`

B

`(1)/(2)H_(2)(g)+(1)/(2)F_(2)(g)toHF(g)`

C

`N_(2)(g)+3H_(2)(g)to2NH_(3)`

D

`CO(g)+(1)/(2)O_(2)(g)toCO_(2)(g)`

Text Solution

Verified by Experts

The correct Answer is:
B

Standard enthalpy of formation is equal to enthalpy change for the preparation of `1` mole of a compound from its standard state.
Therefore, for the reaction
`(1)/(2)H_(2)(g)+(1)/(2)H_(2)(g)toHF(g)`
`DeltaH_(f)^(@)=DeltaH^(@)`
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DINESH PUBLICATION-CHEMICAL THERMODYNAMICS AND CHEMICAL ENERGETICS -Exercise
  1. In thermodynamics, a process is called reversible when

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  2. One mole of non-ideal gas undergoes a change of state (2.0 "atm", 3.0 ...

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  3. Which of the following reactions will define DeltaH(f)^(@) ?

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  4. The enthalpy of vaporisation of a liquid is 30 kJ mol^(-1) and entropy...

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  5. Two moles of an ideal gas is expanded isothermally and reversibly from...

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  6. One mole of monoatomic ideal gas at T(K) is exapanded from 1L to 2L ad...

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  7. An ideal gas is allowed to expand both reversibly and irreversibly in ...

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  8. The standard enthalpy of formation (Delta(f)H^(@)) at 298K for methan...

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  9. (Delta H - Delta U) for the formation of carbon monoxide (CO) from its...

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  10. The enthalpy and entropy change for the reaction, Br(2)(l)+Cl(2)(g)r...

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  11. The enthalpy of hydrogenation of cyclohexene is -119.5kJ mol^(-1). If ...

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  12. The direct conversion of A to B is difficult, hence is carried out by ...

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  13. Consider the following reactions: (i) H^(+)(aq)+OH^(-)(aq)rarrH(2)O(...

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  14. Given the bond energies of H - H and Cl - Cl are 430 kJ mol^(-1) and 2...

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  15. In conversion of lime-stone to lime, CaCO(3(s)) to CaO((s)) + CO(2(g...

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  16. Assuming that water vapour is an ideal gas, the internal energy change...

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  17. Identify the correct statement regarding a spontaneous process.

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  18. The value of log(10)K for a reaction A hArr B is (Given: Delta(f)H(298...

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  19. For the process H(2)O(l) (1 "bar", 373 K) rarr H(2)O(g) (1"bar", 373 K...

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  20. The bond dissociation energies for Cl(2), I(2) and IC l are 242.3, 151...

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